1998
DOI: 10.1016/s0022-0248(98)00621-6
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Suppression of cracks in InxGa1−xSb crystals through forced convection in the melt

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Cited by 48 publications
(37 citation statements)
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“…The use of an alternating magnetic field located in the vicinity of the solid-liquid interface [3], of an internal baffle moving at a constant distance from the interface [4] or the double crucible Czochralski technique [5] have been proposed with the aim of preserving the characteristic of the liquid (concentration, temperature) in a thin layer close to the Solid/Liquid interface, allowing to improve the materials homogeneity. With these methods, most of the melt is used as a feed for the thin liquid layer and a special design is required to limit the interactions between the thin layer and the remaining melt [6].…”
Section: Principle Of Feeding Techniquesmentioning
confidence: 99%
“…The use of an alternating magnetic field located in the vicinity of the solid-liquid interface [3], of an internal baffle moving at a constant distance from the interface [4] or the double crucible Czochralski technique [5] have been proposed with the aim of preserving the characteristic of the liquid (concentration, temperature) in a thin layer close to the Solid/Liquid interface, allowing to improve the materials homogeneity. With these methods, most of the melt is used as a feed for the thin liquid layer and a special design is required to limit the interactions between the thin layer and the remaining melt [6].…”
Section: Principle Of Feeding Techniquesmentioning
confidence: 99%
“…The di±culty of growth of such ternary compounds as GaInAs and GaInSb stems from the large solidus-liquidus separation of the phase diagram and thus a small value of the In segregation coe±cient. The rejected solute accumulates at the interface and is transported by di®usion and convection, the latter having a major e®ect on the quality and the composition uniformity of the grown crystals [2,13]. Various defects such as striations or cellular structure in ternary In-containing crystals leading to poly-crystallinity when the solute concentration exceeds a critical value [47] are often observed.…”
Section: Phase Boundariesmentioning
confidence: 99%
“…Stress caused by the temperature gradients (as well as by the compositional inhomogeneity in ternary compounds induced by segregation) could result in the formation of cracks in brittle crystals. Compositional strain in ternary crystals containing Ga and In could greatly exceed a thermo-elastic one since the tetrahedral radii of the two substituting atoms Ga and In di®er by 12 per cent [13]. When the stress level exceeds a critical value, a plastic creep occurs in the ductile crystals.…”
Section: Assessment Of Crystal Qualitymentioning
confidence: 99%
“…Thermoelasicity problem is three-dimensional even for an axisymmetric crystal, except the case of special orientation of the principal crystal axes [27,47]. Stresses caused by the temperature gradients (as well as by the compositional inhomogeneity in ternary compounds induced by segregation) could result in the formation of cracks in the crystals [9]. When stress level exceeds a critical value, a plastic creep occurs.…”
Section: Mathematical Modelsmentioning
confidence: 99%