Supramolecular architecture of diammonium ferrocene-1,1′-diyldi(methylphosphinate)

Electrochemical Applications of Ferrocene‐Based Coordination Polymers

“…Actually, Fc is one of the units most frequently used to construct redox-active CPs with MOF and other three-dimensional architectures. [60][61][62] This section discusses the synthesis of Fc-CPs, i. e., of CPs with Fc group-containing ligands involved in framework formation. Therefore, the preparation technique of these compounds can be subordinate to conventional (e. g., solvothermal and sonochemical) CP synthesis methods.…”

“…Fc‐CPs can be prepared by a variety of well‐known methods. Actually, Fc is one of the units most frequently used to construct redox‐active CPs with MOF and other three‐dimensional architectures [60–62] . This section discusses the synthesis of Fc‐CPs, i. e., of CPs with Fc group–containing ligands involved in framework formation.…”

Evidence of extremely short hydrogen bond in the homoconjugated ferrocene-1,1′-diyl-bisphosphinic acid anion: sign change of the H/D isotope effect on the 31P NMR chemical shift

“…[17][18][19] Besides, the conformational manifold of intra-and intermolecular hydrogen bonding patterns of Fc(P(R)OOH) 2 in conjunction with the substituent size in the phosphinate group have proven to be paramount for the coordination properties of Fc(P(R)OOH) 2 in novel coordination polymers and metal-organic frameworks with tunable optical, magnetic and redox properties. [20][21][22][23][24] Separate interest is drawn toward H-bonded complexes formed solely by Fc(P(R)OOH) 2 . Along with other phosphorus-containing acids (phosphinic, phosphonic and phosphoric), Fc(P(R)OOH) 2 species possess both proton-donating POH and proton-accepting PQO moieties and are therefore inherently capable of forming H-bonded complexes of two types: electroneutral self-associates [25][26][27] and homoconjugated anions, [28][29][30] i.e.…”

The Phosphinate Group in the Formation of 2D Coordination Polymer with Sm(III) Nodes: X-ray Structural, Electrochemical and Mössbauer Study

“…Compared with carboxylic acids, phosphinate derivatives are characterized by a wide structural diversity, which is mainly achieved due to the ability of phosphinate groups to exhibit various structural functions [13][14][15][16][17][18][19][20]. The variety of coordination polymers and MOF obtained depends on both the substituent at the phosphorus atom of the phosphinate group and the nature of the complexing cation, as well as the experimental conditions (solvent and temperature).…”