Supramolecular organometallic chemistry: the platinum(iv) paradigm

Abstract

Supramolecular chemistry and the chemistry of alkyl derivatives of the transition metals are both topics of considerable current interest, but the combination of the two fields is still underdeveloped. The...

Responsive macrocyclic and supramolecular structures powered by platinum

“…The challenges are, in large part, experimental in nature”. 109 We can further extend this to metalated platinum systems in general. In light of this, there is a pressing need to draw on the skills and innovation of synthetic chemists.…”

Synthesis of (3‐Thienyl)‐Substituted 2,2’‐Bipyridines and Their Application as Activators of Platinum Electrode Catalytic Activity Towards Cholesterol Electrooxidation

“…Platinum complexes with organic ligands are also widely used as electrocatalysts for water reduction in hydrogen energy applications [17] and in the field of (bio)sensing. [18] Platinum complexes with bipyridines [19] and thiophenes [20] are widely recognized in the field, but their ability to electrochemically oxidize or reduce biological analytes has not been previously explored.…”

Supramolecular chemistry of organoplatinum(IV) complexes: A syndiotactic polymer with uracil substituents

“…Specifically, hydrogen bonding groups, including carboxylic acids and the nucleobase uracil can be incorporated in this way (Scheme 1). 21–24 Complexes A and C have been shown to have the structures expected for trans oxidative addition, and they both self-assemble to form supramolecular dimers (Scheme 1). 21…”

“…Specifically, hydrogen bonding groups, including carboxylic acids and the nucleobase uracil can be incorporated in this way (Scheme 1). [21][22][23][24] Complexes A and C have been shown to have the structures expected for trans oxidative addition, and they both self-assemble to form supramolecular dimers (Scheme 1). 21 This paper describes related chemistry using the chelate ligand di-2-pyridylamine [HN(2-C 5 H 4 N) 2 , DPA] in place of the 4,4′-di-t-butyl-2,2′-bipyridine (bubipy) ligand of Scheme 1.…”