Sur une possibilite d'acces aux cetones macrocycliques par les ene-allenes

Bertrand, M.; Dulcère, Jean-Pierre; Gil, G.; Roumestant, M.L.

doi:10.1016/s0040-4039(01)86856-8

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Epoxidation Of Vinylallenes Followed By [4p] Electrocyclization1

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Cited by 25 publications

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“…Subsequent to this initial work, Bertrand and co-workers reported the similar transformation of a macrocyclic vinylallene to form bicyclic cyclopentenones (Scheme 46). 65 The products were described as potential intermediates towards exaltone and muscone.…”

Section: Epoxidation Of Vinylallenes Followed By [4p] Electrocyclizationmentioning

confidence: 99%

The conversion of allenes to strained three-membered heterocycles

et al. 2014

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This article reviews methods for converting allenes to strained, three-membered methylene heterocycles, and also covers the reactivity of these products. Specifically, the synthesis and reactivity of methylene aziridines, allene oxides/spirodiepoxides, methylene silacyclopropanes, methylene phosphiranes, and methylene thiiranes are described, including applications to the synthesis of complex molecules. Due to the primary focus on heterocyclic motifs, the all-carbon analogue of these species (methylene cyclopropane) is only briefly discussed.

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Section: Epoxidation Of Vinylallenes Followed By [4p] Electrocyclizationmentioning

confidence: 99%