1999
DOI: 10.1006/jcis.1999.6289
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Surface Chemical Studies on the Competitive Adsorption of Poly(acrylic acid) and Poly(vinyl alcohol) onto Alumina

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Cited by 107 publications
(88 citation statements)
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“…The adsorption rises steeply at low polymer concentrations indicating a high-affinity type adsorption. Figure 2 represents the adsorption density of PAA as a function of equilibrium concentration of the polymer in supernatant on the surface of alumina particles at pH 7 and, as can be observed, a plateau was reached at approximately 0.70 mg m surface coverage, which is in good agreement with the results of earlier investigators (e.g., 8,9). The adsorption density of PAA on the surface of silica particles at pH 7 was not significant indicating that no adsorption of PAA occurs on the face of kaolin particles.…”
Section: Adsorption Studiessupporting
confidence: 90%
“…The adsorption rises steeply at low polymer concentrations indicating a high-affinity type adsorption. Figure 2 represents the adsorption density of PAA as a function of equilibrium concentration of the polymer in supernatant on the surface of alumina particles at pH 7 and, as can be observed, a plateau was reached at approximately 0.70 mg m surface coverage, which is in good agreement with the results of earlier investigators (e.g., 8,9). The adsorption density of PAA on the surface of silica particles at pH 7 was not significant indicating that no adsorption of PAA occurs on the face of kaolin particles.…”
Section: Adsorption Studiessupporting
confidence: 90%
“…These groups have great influence on the adsorption properties of PVA, providing a chemical conformation of the polymer with a structure with more loops and tails adsorbed better to the surface of the alumina particle [30]. Acetate groups are also sensitive to pH with the level of interactions increasing with pH [29,31]. Wiśniewska et al [29] have demonstrated that there is a stability pH range between 3 and 6 for alumina suspension and that beyond the PVA is more stretched and thus the adsorption of the polymer chain is on few particles, causing bridging flocculation of suspension.…”
Section: 2mentioning
confidence: 99%
“…4a indicates hydrogen bond formed in the ZnS:Ni 2? /PEG interface (Santhiya et al 1999). The spectrum of CTAB is presented in Fig.…”
Section: Ft-ir Studymentioning
confidence: 99%