Surface Chemistry Directs the Tunable Assembly of TiO<sub>2</sub> Anatase Nanocubes into Three‐Dimensional Mesocrystals

Huesmann, H.; Schechtel, Eugen; Lieberwirth, Ingo; Panthöfer, Martin; Tremel, Wolfgang

doi:10.1002/ejic.201900376

Cited by 2 publications

(1 citation statement)

References 61 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In general, such systems containing NCs as building units can be characterized as colloidal crystals [35]. A special subspecies of these colloidal crystals are mesocrystals [36][37][38][39][40]. As soon as the NC subunits that build up a colloidal crystal are anisotropic and the alignment of those occurred on a long-range order, one can speak of a mesocrystal [41,42].…”

Section: Introductionmentioning

confidence: 99%

Environmentally Benign Formation of Nickel Hexacyanoferrate-Derived Mesoframes for Heterogeneous Catalysis

et al. 2021

View full text Add to dashboard Cite

The tetramethylammonium hydroxide (TMAH)-controlled alkaline etching of nickel hexacyanoferrate (NiHCF) mesocrystals is explored. The alkaline etching enables the formation of hollow framework structures with an increased surface area, the exposure of active Ni and Fe sites and the retention of morphology. The ambient reaction conditions enable the establishment of a sustainable production. Our work reveals novel perspectives on the eco-friendly synthesis of hollow and colloidal superstructures for the efficient degradation of the organic contaminants rhodamine-B and bisphenol-A. In the case of peroxomonosulfate (PMS)-mediated bisphenol-A degradation, the rate constant of the etched mesoframes was 10,000 times higher indicating their significant catalytic activity.

show abstract

Section: Introductionmentioning

confidence: 99%

Environmentally Benign Formation of Nickel Hexacyanoferrate-Derived Mesoframes for Heterogeneous Catalysis

et al. 2021

View full text Add to dashboard Cite

show abstract

Further Sustainable and/or Unconventional Low-temperature Wet-chemical Synthetic Methods

Barbon,

Tajoli,

Spolaore

et al. 2024

Unconventional Green Synthesis of Inorganic Nanomaterials

View full text Add to dashboard Cite

This chapter focuses on a series of further sustainable and/or unconventional wet-chemical methods to prepare single metal, alloys, oxides, chalcogenides and other inorganic compounds in the form of nanoparticles (NPs) at low temperature (<200 °C). In particular, the aim of the chapter is to provide the reader with an overview of further methods not specifically addressed by other chapters of the book, such as hydrothermal, polyol-assisted, continuous-flow and sonochemical methods, as well as radiochemistry and laser ablation in liquid media. A theoretical background of each method, a description of the synthetic procedure and a discussion of the synthetic parameters involved, and their influence on the final features of the products, are given, with the pros and cons of the presented synthetic approaches also outlined. In addition, a description of the state-of-the-art of the compounds obtainable through each approach is presented.

show abstract

Surface Chemistry Directs the Tunable Assembly of TiO₂ Anatase Nanocubes into Three‐Dimensional Mesocrystals

Cited by 2 publications

References 61 publications

Environmentally Benign Formation of Nickel Hexacyanoferrate-Derived Mesoframes for Heterogeneous Catalysis

Environmentally Benign Formation of Nickel Hexacyanoferrate-Derived Mesoframes for Heterogeneous Catalysis

Further Sustainable and/or Unconventional Low-temperature Wet-chemical Synthetic Methods

Contact Info

Product

Resources

About

Surface Chemistry Directs the Tunable Assembly of TiO2 Anatase Nanocubes into Three‐Dimensional Mesocrystals

Cited by 2 publications

References 61 publications

Environmentally Benign Formation of Nickel Hexacyanoferrate-Derived Mesoframes for Heterogeneous Catalysis

Environmentally Benign Formation of Nickel Hexacyanoferrate-Derived Mesoframes for Heterogeneous Catalysis

Further Sustainable and/or Unconventional Low-temperature Wet-chemical Synthetic Methods

Contact Info

Product

Resources

About

Surface Chemistry Directs the Tunable Assembly of TiO₂ Anatase Nanocubes into Three‐Dimensional Mesocrystals