Surface chemistry of organophosphorus compounds

Abstract

vibrational/rotational-to-electron energy flow can be facile in anions with weakly bound electrons and may give rise to electron ejection at rates approaching 10" s-I. Treatment of these prospects will also have to wait until publication of the full paper; the primary purpose of the present Letter is to communicate these first predictions about the existence of new electronically bound and potentially metastable states of these DR anions. It is our desire to nurture interest in these systems within the experimental J. Phys. Chem. 1988, 92, 6182-6188 community, especially with respect to developing new sources for these species. This paper reviews the known decomposition chemistry of organophosphorus compounds interacting with metal and metal oxide surfaces. Three kinds of processes-oxidation, dealkylation, and hydrolysis-are known to be important, but the fundamental knowledge base in this technologically and environmentally important area is presently inadequate. Some significant research directions are identified for surface chemical science, surface reaction chemistry, solid-state synthesis, and organometallic cluster chemistry.

Microwave‐Assisted Synthesis of Nanocrystalline MgO and Its Use as a Bacteriocide

“…[17,18] MgO in particular has shown great promise as a destructive adsorbant for toxic chemical agents. [19,20] Of the many methods employed today for the fabrication of nanomaterials, the use of microwave (MW) radiation is the one which perhaps requires the smallest investment in equipment, since it can be carried out in a domestic MW oven. MWs have found a number of applications in chemistry since 1986.…”

Use of NMR techniques for toxic organophosphorus compound profiling

“…OP compounds degrade more easily in the environment [116], but the environmental impact of their degradation products is still not well defined. There are a large variety of the possible OP compound degradation pathways, of which hydrolysis and oxidation are the most typical [116], but other modes of degradation of photochemistry [117,118] and surface chemistry [119] have also been investigated. The environmental decomposition of CWA has also been under study.…”

Comparative Study of Decomposition adsorption of Sarin on ZnnOnand CdnOn(n=1,4), by Theoretical Method

“…Hence, researchers prefer to use theoretical methods to investigate their decomposition possibility. The nano metal oxides with low coordination number 3 have unusual electronic properties and adsorption behavior due to their defect sites (Frenkel&Schottky), Lewis acid (metal cations) sites, Lewis base (oxide anions) sites and, high surface area 4,5 . Decomposition adsorptionof Chemical warfareagents (CWAs) on nano metal oxides yields non-toxic products.Dimethyl methylphosphonate, [ …”