Surface Complexation of Chromium(VI) on Iron(III) Hydroxide: Mechanisms and Stability Constants of Surfaces Complexes

Abstract

The adsorption of chromate ions H2-yA (y = 1, 2, and A = CrO42–) on iron(III) hydroxide was conducted as a function of adsorbent mass, solution pH, and hydration time. The surface complexation technique, based on the examination of the chromate distribution between the solid and liquid phases, was adopted to predict the adsorption mechanism. To specify stoichiometry of the chromate surface complexes, the proton (n > 0), and hydroxyl (n < 0) ion-exchange was evaluated at a pH range of 2–12. The obtained “n” values are ranging between -1 and 1. As a result, the sorption process involved specific chemical interaction with surface sites, resulting in 1H+ and 1OH– release of the adsorbate molecule. The surface species identified were ; ; ; ; ; ; ; and . The logarithmic values of their complexing constants were: log K00 = 1.81 ± 0.04; log K11 = -3.53 ± 0.07; log K21 = -1.03 ± 0.23, log K1-1 = 7.15 ± 0.14 and log K2-1 = 9.62 ± 0.53. The results showed that the chromate adsorption on Fe(III) hydroxide was of electrostatic and chemical nature at pH lower than 5.5, and only of chemical nature at pH superior to 5.5. Taking into account these considerations, Fe(III) hydroxide could be considered an excellent sorbent for the removal of Cr(VI) from wastewater solutions.

Optimization and mechanisms of rapid adsorptive removal of chromium (VI) from wastewater using industrial waste derived nanoparticles

“…The proposed figure exhibits the different interactions involved in the Cr(VI) adsorption process including electrostatic interactions (i), Complexation (ii) Pore filling (iii) and Reduction process (iv): Electrostatic interaction The negatively charged Cr(VI) species, under acidic condition, were favorably migrated to the positively charged surfaces of nWTRs (Al, Fe oxides and OH atoms) (The OH atoms is protonated under acidic conditions to produce—OH 2 + ) 54 . Complexation The Cr(VI) ions could form inner sphere complexes with Fe/Al oxides of nWTRs with a more pronounced effect in acid conditions 55 . Pore filling Chromium ions possibly trapped in the micropores of nWTRs surface because the pores size of the nWTRs are larger than the radiuses of HCrO 4 − and Cr 2 O 7 ions 56 .…”

“…Complexation The Cr(VI) ions could form inner sphere complexes with Fe/Al oxides of nWTRs with a more pronounced effect in acid conditions 55 .…”

Surface Complexes of Cr(VI) by Eucalyptus Barks

“…As found previously, Cr(VI) recovery is strongly acidic dependent and shows maximum retention, for various sorbent amounts, at pH around 2. As a consequence, this retention is attributed to HCrO species that are predominant between pH 1 and 6.5 [40].…”