Surface energy and surface reorganization of perfluorohexylethyl methacrylate/n-alkyl (meth)acrylate copolymers

Gu, Zixu; Zhang, Mingzu; He, Jinlin; Ni, Peihong

doi:10.1016/j.colsurfa.2016.05.016

Cited by 16 publications

(6 citation statements)

References 38 publications

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“… 80 Usually, the surface reorganization of the fluorinated chains is directly associated with the T g or T m of these copolymers. 66 However, no clear relationship can be found in our case (see Table S4 in the ESI † ) beyond the evident difference in T g values of polystyrene and poly(DFMST- co -ST) copolymers.…”

Section: Resultscontrasting

confidence: 60%

“…As expected, compared with previous results, 36 the CA values decrease significantly when CF 3 is replaced by CF 2 H. The obtained CA results are in satisfactory agreement with those of previous studies on the perfluorohexylethyl(meth)acrylate/ n -alkyl (meth)acrylate copolymers. 66 Gu et al 66 found that the groups (H or CH 3 ) at α-position of (meth)acrylate significantly influenced the contact angle, while the increase of side-chain lengths in the two types of copolymers did not.…”

Section: Resultsmentioning

confidence: 99%

“…The surface reorganization has been one of the key analyzed properties of the copolymers in recent years. [66][67][68][69][70] Subsequently, to examine such a characteristic of copolymers, the effect of the comonomer structure on the surface energy is studied. To the best of our knowledge, there is a number of reports about the inuence of wettability and oil repellency of uorinated copolymers, depending on their structure.…”

Section: Contact Angle and Surface Energy Of The Uorinated Copolymersmentioning

confidence: 99%

“…To the best of our knowledge, there is a number of reports about the inuence of wettability and oil repellency of uorinated copolymers, depending on their structure. 66,67,71 The advancing and receding contact angles of two liquids (polar and nonpolar) on the copolymer layers and the contact angle hysteresis (CAH) allowed us to get insight on the surface energy of these new uorocopolymers. These layers were prepared via deposition of poly(DFMST-co-ST) copolymers on the glass surface beforehand modied by octadecyltrichlorosilane (OTS) according to a previous publication.…”

Section: Contact Angle and Surface Energy Of The Uorinated Copolymersmentioning

confidence: 99%

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Aromatic fluorocopolymers based on α-(difluoromethyl)styrene and styrene: synthesis, characterization, and thermal and surface properties

et al. 2018

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Section: Resultscontrasting

confidence: 60%

Section: Resultsmentioning

confidence: 99%

Section: Contact Angle and Surface Energy Of The Uorinated Copolymersmentioning

confidence: 99%

Section: Contact Angle and Surface Energy Of The Uorinated Copolymersmentioning

confidence: 99%

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Aromatic fluorocopolymers based on α-(difluoromethyl)styrene and styrene: synthesis, characterization, and thermal and surface properties

et al. 2018

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“…The phenomenon will lead to the increase of surface free energy due to the surface reorganization, which limits the practical application of WFPUs. Thus, it is very significant to design WFPUs with stable lower surface free energy through decreasing surface reorganization when the films may contact with water or moist air.…”

Section: Introductionmentioning

confidence: 99%

Effect of crosslinking on the surface free energy and surface reorganization of waterborne fluorinated polyurethane

Yang

et al. 2018

J of Applied Polymer Sci

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To endow waterborne fluorinated polyurethanes (WFPUs), films with stable lower surface free energy and lower surface reorganization after the films contacted with water, a series of crosslinked WFPUs (CWFPUs) emulsions were prepared by adjusting the content of aziridine (AZ). The effect of crosslinking on the surface free energy, glass-transition temperature (T g ), water absorption, and surface composition of dry/hydrated WFPUs and CWFPUs films were studied by CAs test, dynamic mechanical analysis, water absorption measurements, and X-ray photoelectron spectroscopy. When the fluorine content was 0.5%, the surface free energy of the CWFPUs films modified by 0.4% AZ content (CWFPU-6-0.5-CK0.4) reached to the lowest value of 15.76 mN m −1 which almost equaled to the surface free energy (15.45 mN m −1 ) of the dry uncrosslinked films (WFPU-6-0.5). With the increasing of AZ content, the T g, hard of hard segments of the CWFPUs films increased and the water absorption of the CWFPUs films decreased, which suggested the formation of the crosslinked network structures. The studies of the surface elements and groups composition of dry/hydrated WFPUs and CWFPUs both confirmed that the surface reorganization and the migration of fluorinated side chains were restricted by the crosslinked network structures.

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Effect of sequence structure on wetting behaviors of fluorinated methacrylate polymers based on perfluorohexylethyl methacrylate and stearyl acrylate

Cheng

Zhang

et al. 2017

Chin J Polym Sci

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Surface energy and surface reorganization of perfluorohexylethyl methacrylate/n-alkyl (meth)acrylate copolymers

Cited by 16 publications

References 38 publications

Aromatic fluorocopolymers based on α-(difluoromethyl)styrene and styrene: synthesis, characterization, and thermal and surface properties

Aromatic fluorocopolymers based on α-(difluoromethyl)styrene and styrene: synthesis, characterization, and thermal and surface properties

Effect of crosslinking on the surface free energy and surface reorganization of waterborne fluorinated polyurethane

Effect of sequence structure on wetting behaviors of fluorinated methacrylate polymers based on perfluorohexylethyl methacrylate and stearyl acrylate

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