2024
DOI: 10.1021/acsami.4c02927
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Surface Engineering of Anodic WO3 Layers by In Situ Doping for Light-Assisted Water Splitting

Karolina Syrek,
Sebastian Kotarba,
Marta Zych
et al.

Abstract: This study presents a novel approach to fabricating anodic Co−F−WO 3 layers via a single-step electrochemical synthesis, utilizing cobalt fluoride as a dopant source in the electrolyte. The proposed in situ doping technique capitalizes on the high electronegativity of fluorine, ensuring the stability of CoF 2 throughout the synthesis process. The nanoporous layer formation, resulting from anodic oxide dissolution in the presence of fluoride ions, is expected to facilitate the effective incorporation of cobalt … Show more

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