Surface forms of unsaturated hydrocarbons and their transformations on group VIII metals

Kharson, M. S.; Davidov, E. M.; Kiperman, S. L.

doi:10.1007/bf02279779

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Optimal Bond Energies Of Surface Compounds2

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1999

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Cited by 5 publications

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“…On the other side, the high reactivity may be also exerted by surface compounds tightly bound to the catalyst. Such a case was observed on studying the isomerization and hydrogenolysis of C 5 paraffins on platinum-alumina catalyst (80).…”

Section: Optimal Bond Strengths Of Reactive Surface Compoundsmentioning

confidence: 96%

Stationary and Nonstationary Kinetic Studies Related to the Mechanism of Heterogeneous Catalytic Reactions

Kiperman

Kumbilieva

1997

Ind. Eng. Chem. Res.

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Some results on the kinetics and mechanism of catalytic processes obtained by use of a complex strategy, including combined stationary and nonstationary investigations, are discussed. The approach developed is grounded on exact kinetic studies by gradientless methods, isotopic exchange, IR spectroscopy of surface compounds, isotopic effects, adsorption measurements, investigations of transition processes, and catalyst deactivation. The reaction kinetics is related to the specificity in the mechanism of processes under investigation.

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