Surface functionalization of nitrogen-doped carbon derived from protein as anode material for lithium storage

An, Geon‐Hyoung; Kim, Hyeonjin; Ahn, Hyo‐Jin

doi:10.1016/j.apsusc.2018.08.201

Cited by 29 publications

(11 citation statements)

References 51 publications

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“…[1][2][3][4] Among them, lithium-ion batteries (LIBs) have attracted attention because of their high energy density and adequate cycle life. [5][6][7][8][9] However,the scarcity and high price of lithium resources limits the development of LIBs.Incontrast, the widespread production and low cost of sodium has directed attention to sodium-ion batteries (NIBs), which are considered apromising substitute for LIBs. [10,11] Unfortunately,the higher redox potential of Na/Na + (À2.71 Vvs.…”

Section: Introductionmentioning

confidence: 99%

A Robust Solid Electrolyte Interphase Layer Augments the Ion Storage Capacity of Bimetallic‐Sulfide‐Containing Potassium‐Ion Batteries

et al. 2019

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Metal-organic framework-derived NiCo 2.5 S 4 microrods wrapped in reduced graphene oxide (NCS@RGO) were synthesized for potassium-ion storage.Upon coordination with organic potassium salts,N CS@RGO exhibits an ultrahigh initial reversible specific capacity (602 mAh g À1 at 50 mA g À1 ) and ultralong cycle life (a reversible specific capacity of 495 mAh g À1 at 200 mA g À1 after 1900 cycles over 314 days). Furthermore,t he battery demonstrates ah igh initial Coulombic efficiency of 78 %, outperforming most sulfides reported previously.A dvanced ex situ characterization techniques,i ncluding atomic force microscopy, were used for evaluation and the results indicate that the organic potassium salt-containing electrolyte helps to form thin and robust solid electrolyte interphase layers,w hichr educe the formation of byproducts during the potassiation-depotassiation process and enhance the mechanical stability of electrodes.T he excellent conductivity of the RGO in the composites,a nd the robust interface between the electrodes and electrolytes,i mbue the electrode with useful properties;i ncluding,u ltrafast potassium-ion storage with areversible specific capacity of 402 mAh g À1 even at 2Ag À1 .

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Section: Introductionmentioning

confidence: 99%

A Robust Solid Electrolyte Interphase Layer Augments the Ion Storage Capacity of Bimetallic‐Sulfide‐Containing Potassium‐Ion Batteries

et al. 2019

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“…[1][2][3][4][5] Unfortunately,o wing to the inhomogeneousd istributiona nd limiteda vailability of lithium resources, LIBsa re subjectt os evere cost problems for their future large-scale energy storage applications. [1][2][3][4][5] Unfortunately,o wing to the inhomogeneousd istributiona nd limiteda vailability of lithium resources, LIBsa re subjectt os evere cost problems for their future large-scale energy storage applications.…”

Section: Introductionmentioning

confidence: 99%

“…In the past decade, lithium-ion batteries (LIBs) have been one of the prominent energy storages ystemsa nd broadly utilized in many electronic devices owing to their high energy density and long cycling life. [1][2][3][4][5] Unfortunately,o wing to the inhomogeneousd istributiona nd limiteda vailability of lithium resources, LIBsa re subjectt os evere cost problems for their future large-scale energy storage applications. [6] As ah opefula lternative candidate to LIBs, potassium-ion batteries (KIBs) have attracted considerable attention because the potassium source is more abundant than lithium in the Earth's crust.…”

Section: Introductionmentioning

confidence: 99%

Direct Growth of MoO₂/Reduced Graphene Oxide Hollow Sphere Composites as Advanced Anode Materials for Potassium‐Ion Batteries

et al. 2019

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Hollow MoO2/reduced graphene oxide (MoO2/rGO) sub‐microsphere composites have been fabricated through a simple hydrothermal approach followed by a heat treatment process. When employed as an anode material for potassium‐ion batteries, the as‐synthesized MoO2/rGO composite can deliver an initial charge specific capacity of 367.2 mAh g−1 at 50 mA g−1, and its reversible capacity is 218.9 mAh g−1 after 200 cycles. Even when cycled at 500 mA g−1, a high charge specific capacity of 104.2 mAh g−1 is achieved after 500 cycles. The excellent cycling capability and rate performance may be ascribed to the synergistic effects of the reduced graphene oxide and the hollow MoO2 spheres, which can increase the electrical conductivity of the composite, as well as resisting the strain arising from the repeated discharge–charge processes. These results indicate that the MoO2/rGO hollow sphere composites are promising negative electrode materials for potassium‐ion batteries.

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“…Nowadays, lithium‐ion rechargeable batteries (LIBs) are commonly used in mobile electronic devices, electric vehicles, and large‐scale energy storage systems, owing to the high energy density, no memory effect, and low self‐discharge rate . However, commercial graphite anodes can't meet the energy demand with a theoretical capacity of 372 mAh g −1 .…”

Section: Introductionmentioning

confidence: 99%

In Situ Wrapping SiO with Carbon Nanotubes as Anode Material for High‐Performance Li–Ion Batteries

Wang

Liu³

et al. 2019

ChemistrySelect

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Silicon-based material as lithium-ion anodes has attracted huge attention owing to their ultrahigh capacity. However, they usually undergo severe volume expansion over the repeated lithiation/delithiation processes and have low electronic conductivity, leading to the inferior cycling stability and the poor rate capability. Here, an in-situ growth of carbon nanotubes (CNTs) on the surface of SiO composite was prepared and then encapsulated by the amorphous carbon derived from high softening point pitch. SEM and TEM studies show that SiO was firmly wrapped with CNTs and well coated with the amorphous carbon. Meanwhile, nitrogen adsorption-desorption measurement indicated the prepared composite SiO@CNTs/C was hierarchical pore structure, which can shorten the lithium-ion transport pathway and enhance the structural stability. The prepared SiO@CNTs/C exhibited an excellent long-term cycling stability (a high reversible specific capacity of 821.7 mAh g À 1 , and a high capacity retention of 95.9% to the 3rd cycle after 200 cycles), and prominent rate capacity, indicating the great potential of SiO@CNTs/C anode for practical application.[a] Dr.

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Surface functionalization of nitrogen-doped carbon derived from protein as anode material for lithium storage

Cited by 29 publications

References 51 publications

A Robust Solid Electrolyte Interphase Layer Augments the Ion Storage Capacity of Bimetallic‐Sulfide‐Containing Potassium‐Ion Batteries

A Robust Solid Electrolyte Interphase Layer Augments the Ion Storage Capacity of Bimetallic‐Sulfide‐Containing Potassium‐Ion Batteries

Direct Growth of MoO₂/Reduced Graphene Oxide Hollow Sphere Composites as Advanced Anode Materials for Potassium‐Ion Batteries

In Situ Wrapping SiO with Carbon Nanotubes as Anode Material for High‐Performance Li–Ion Batteries

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Surface functionalization of nitrogen-doped carbon derived from protein as anode material for lithium storage

Cited by 29 publications

References 51 publications

A Robust Solid Electrolyte Interphase Layer Augments the Ion Storage Capacity of Bimetallic‐Sulfide‐Containing Potassium‐Ion Batteries

A Robust Solid Electrolyte Interphase Layer Augments the Ion Storage Capacity of Bimetallic‐Sulfide‐Containing Potassium‐Ion Batteries

Direct Growth of MoO2/Reduced Graphene Oxide Hollow Sphere Composites as Advanced Anode Materials for Potassium‐Ion Batteries

In Situ Wrapping SiO with Carbon Nanotubes as Anode Material for High‐Performance Li–Ion Batteries

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Direct Growth of MoO₂/Reduced Graphene Oxide Hollow Sphere Composites as Advanced Anode Materials for Potassium‐Ion Batteries