Surface Modification Effect on V-Doped Ti₃C₂T_x as Bifunctional Catalyst Electrodes for Symmetric Supercapacitor and the Hydrogen Evolution Reaction

Abstract

MXene-based composite materials have plenty of characteristics, such as high surface area, excellent metallic conductivity, rapid oxidation, and reduction activity. These materials have many advantages for use in modified electrodes for energy storage and conversion applications. However, their applicability in several types of industries has been significantly limited as a result of issues with surface aggregation and oxidation. In this study, we improved the electrochemical properties of the electrodes by modifying the surface of the layered Ti 3 C 2 T x material. KOH is used to alkalize Ti 3 C 2 T x , and −OH is replaced by F. The surface hydroxyl groups can be eliminated through intercalation with K + . This study reports on the synthesis of vanadiumdoped layered Ti 3 C 2 T x nanosheets intercalated with K + using a hydrothermal synthesis method. The resulting material serves as a bifunctional catalyst for electrochemical supercapacitors and hydrogen evolution. The V (0.05)-doped K + −Ti 3 C 2 T x electrodes demonstrated a superior specific capacitance of 670 F g −1 when an applied current of 1 A g −1 was used in the three-electrode system. The symmetric supercapacitor device was constructed using the V (0.05)-doped K + −Ti 3 C 2 T x electrode, which delivered a high specific energy (110 Wh kg −1 ) and power density (1804.91 W kg −1 ). The symmetric capacitance of the electrode is 220.2 F g −1 at a current density of 1 A g −1 , and it exhibits an admirable specific capacity retention of 97.8% after 10 000 cycles. Furthermore, the K + − Ti 3 C 2 T x layered electrocatalyst doped with V (0.05) exhibits a low overpotential of 300 mV at 10 mA/cm 2 and low Tafel slope values of 105 mV dec −1 for the hydrogen evolution reaction in an acidic medium.

Basic and acidic electrolyte mediums impact on MnO2-Mn2O3/Poly-2-methylaniline hexagonal nanocomposite pseudo-supercapacitor

“…This feature aligns with the growing demand for energy storage systems that not only deliver high performance but also exhibit longevity and resilience [4,5]. The enduring ability of metal oxides, particularly in composite or spinel configurations, to retain charge significantly contributes to the advancement of supercapacitors capable of meeting the demands across various applications [6][7][8][9][10].…”

Can Doped-MXene-Based Supercapacitors Be the Game-Changer for Future Energy Landscape? A Critical Perspective

“…The capacitance values are shown in Figure h . In another work, Ramadoss et al observed the improvement in the charge storage behavior of the MXene after V-doping on the layered K + -Ti 3 C 2 T x , which is shown in Figure i . Fatima et al incorporated Nb atoms into the MXene in order to improve its ionic conductivity and stability.…”

“…(i) CV and GCD curves of various V-doped K + -Ti 3 C 2 T x . Reprinted with permission from ref . Copyright 2023 American Chemical Society.…”