A TIG surface alloying process was applied to modify the surface of ductile cast iron samples. Using this process, in-situ metal matrix composite (MMC) layers were produced on samples to improve their wear resistance. These layers were made by melting substrates and powders as additional material into this melt pool. The efficiency of preheating of the samples to prevent cold cracks during solidification was verified. Moreover, a buffer layer produced in situ to decrease the mismatches between the chemical and physical properties of the materials was also tested. Post-weld heat treatment (PWHT) was used to increase the tribological characteristics of the layers and eliminate adverse effects of the heat-affected zone (HAZ) created by the fusion of the substrate surface. The results showed that, in the samples without preheating, the formation of cold cracks occurred. Additionally, layers produced without a buffer layer showed defects, such as shrinkage and porosity. However, using both preheating and a buffer layer prevented cold cracks, discontinuities, shrinkage, and porosity defects in the layers. Furthermore, PWHT allowed for the transformation of brittle martensite into tempered martensite at the HAZ. MMC layers presented high hardness of up to 1230 HV and wear resistance up to 5.8 times greater compared to the substrate samples without layers.