2009
DOI: 10.1007/s12221-009-0065-1
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Surface modification of okra bast fiber and its physico-chemical characteristics

Abstract: The effect of chemical treatment i.e. bleaching, alkalization and graft copolymerization on the morphology changes of okra bast fiber has been investigated by means of infrared spectroscopy (IR), scanning electron microscopy (SEM), water absorption and tensile properties measurements. The graft copolymerization reaction of bleached fiber with acrylonitrile monomer (AN) has been carried out under the catalytic influence of K 2 S 2 O 8 and FeSO 4 redox system. The maximum graft yield (11.43 %) has been found at … Show more

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Cited by 93 publications
(24 citation statements)
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“…b–d). The increase in the smoothness of the treated fibers surface can also be explained by the partial removal of lignin and hemicelluloses from these fibers . Slight defibrillation may be macroscopic evidence of the limited cleavage of cellulose detected for the AA and AA_EP‐treated BPFs by Raman spectroscopy.…”
Section: Resultsmentioning
confidence: 94%
“…b–d). The increase in the smoothness of the treated fibers surface can also be explained by the partial removal of lignin and hemicelluloses from these fibers . Slight defibrillation may be macroscopic evidence of the limited cleavage of cellulose detected for the AA and AA_EP‐treated BPFs by Raman spectroscopy.…”
Section: Resultsmentioning
confidence: 94%
“…More reactive groups are exposed on the fiber surface by chemical treatment, which in turn gives better interface and enhanced mechanical properties of the composite [54]. Some chemical surface modification techniques include treatment with sodium chlorite [55], metha acrylate [56], isocyanate [57], silane treatment [58], acetylation [59, 60], mercerization [6164], etherification [65, 66], enzymatic treatment [6771], peroxide treatments [62], benzoylation [61], dicumyl peroxide treatment [57], plasma treatment [7275], ozone treatments [76,77], and grafting [7880]. The oxidation of polyolefin [81,82] has also been reported to improve the incompatibility between the surfaces of natural fiber and polymer matrix.…”
Section: Modification Of Natural Fibersmentioning
confidence: 99%
“…Then the fiber was washed with 0.05 M acetic acid and then with distilled water until it became neutral. The alkali treated fiber was stored after drying in oven at 80 °C for 6 h. The jute fiber (20 g) was bleached in 1 L of sodium chlorite (NaClO2, 7g.L −1 ) solution according to our previous study (Khan et al 2009). For acetylation, alkali-treated jute fiber was soaked in glacial acetic acid for 1 h at 30 °C.…”
Section: Preparation Of Jute Samplementioning
confidence: 99%
“…The bleached jute fiber was grafted by acrylonitrile monomer (50 wt.% of fiber) in the presence of K2S2O8 as initiator (1 wt.% of fiber), and FeSO4 as a catalyst. The reaction was carried out at 70 °C in a water bath for 90 min (Khan et al 2009). The bleached fiber was also immersed on toluene solution containing diphenyl methanediisocyanate.…”
Section: Preparation Of Jute Samplementioning
confidence: 99%