Surface modification of Ti3C2Tx using terminal groups and heteroatoms with excellent electrochemical performance in supercapacitors

Abstract

Surface modification of Ti3C2Tx greatly enhances its charge storage mechanism as an electrode material. Herein, we demonstrate the role of surface terminals and heteroatoms in the electrochemical behavior of Ti3C2Tx electrodes. The abundance of –F and –OH surface terminals may be obtained with an acidic or base medium while etching of Ti3C2Tx. Further treatment with ammonia or glucose may help to get a thin layer of N or C at the surface of Ti3C2Tx. It is found that abundant reaction sites and larger interlayer spacing can help in improving the specific capacitance by nearly 2.5 times to unmodified Ti3C2Tx electrodes. This superior performance can be achieved without sacrificing the conductivity and accordion-like structure of Ti3C2Tx MXene two-dimensional material.

Plasmon assisted Ti3C2Tx grafting and surface termination tuning for enhancement of flake stability and humidity sensing performance

“…Commonly, high energy treatments, such as temperature annealing or plasma processing, are used to tune the surface chemistry of MXenes. 10,[35][36][37] However, such rough methods can damage the MXenes structure and lead to a loss of functionality of the akes. As an alternative, few chemical approaches capable of changing the akes surface composition were proposed.…”