A promising
magnetocaloric effect has been obtained in Ni–(Co)–Mn–X
(X = Sn, In, Sb)-based Heusler alloys, but the low isothermal magnetic
entropy change ΔS
M restricts the
further promotion of such materials. Defect engineering is a useful
method to modulate magnetic performance and shows great potential
in improving the magnetocaloric effect. In this work, dense Ni vacancies
are introduced in Ni41Mn43Co6Sn10 alloys by employing high-energy electron irradiation to
adjust the magnetic properties. These vacancies bring about intense
lattice distortion to change the distance between adjacent magnetic
atoms, leading to a significant enhancement of the average magnetic
moment. As a result, the saturation magnetization of ferromagnetic
austenite is accordingly improved to generate a high isothermal magnetic
entropy change ΔS
M of 20.0 J/(kg
K) at a very low magnetic field of ∼2 T.