A compound process that integrates end electrical discharge (ED) milling and mechanical grinding to machine silicon carbide (SiC) ceramics is developed in this paper. The process employs a turntable with several uniformly-distributed cylindrical copper electrodes and abrasive sticks as the tool, and uses a water-based emulsion as the machining fluid. End electrical discharge milling and mechanical grinding happen alternately and are mutually beneficial, so the process is able to effectively machine a large surface area on SiC ceramic with a good surface quality. The machining principle and characteristics of the technique are introduced. The effects of polarity, pulse duration, pulse interval, open-circuit voltage, discharge current, diamond grit size, emulsion concentration, emulsion flux, milling depth and tool stick number on performance parameters such as the material removal rate, tool wear ratio, and surface roughness have been investigated. In addition, the microstructure of the machined surface under different machining conditions is examined with a scanning electron microscope and an energy dispersive spectrometer. The SiC ceramic was mainly removed by end ED milling during the initial rough machining mode, whereas it is mainly removed by mechanical grinding during the later finer machining mode; moreover, the tool material can transfer to the workpiece surface during the compound process. Over the last few years, there has been a great upsurge of interest in advanced ceramic materials. As a result of this interest, significant advances in the development and use of ceramic materials have been made, and the world markets for advanced ceramics are growing. Of the various ceramic materials, silicon carbide (SiC) ceramics are the most interested engineering ceramics because of their combination of outstanding mechanical, physical and chemical properties such as low density, high strength, high thermal conductivity, low thermal expansion coefficient and wear and high corrosion resistance even at elevated temperature [1][2][3]. The broad range of technological applications presently served by SiC ceramics includes cutting tools, automotive engine parts, heat exchangers, high temperature bearings, heavyduty electric contacts, fixtures, nozzles, turbine blades and many more applications [4][5][6]. However, the properties that make these materials appealing to use also create a major challenge in traditional diamond grinding or diamond turning, because of their great hardness and brittleness [7,8]. Electrical discharge machining (EDM) is a thermoelectric process, whereby material is removed by a succession of electrical discharges occurring between an electrode and a workpiece which is immersed in a dielectric liquid medium. Unlike traditional cutting and grinding processes, which rely on the force generated by a harder tool or abrasive material to remove the softer work-material, the EDM process utilizes electrical sparks or thermal energy to erode the unwanted material and generate the desired shape. Since no...