Surface-Modified CeO₂-Octahedron-Supported Pt Nanoparticles as Ethylene Scavengers for Fruit Preservation

Abstract

Catalytic oxidation of ethylene associated with the preservation of fruits and vegetables (F&V) at low temperatures remains challenging. To address this issue, CeO2-octahedron-supported Pt catalysts were synthesized and modified by capacitively coupled plasma for efficient catalytic oxidation of C2H4. After the plasma treatment, CeO2 with rich oxygen vacancies was created, which acted as a support to facilitate the regulation of the size and dispersion of Pt nanoparticles. Compared with Pt/pristine CeO2, the Pt/plasma-modified CeO2 catalyst (Pt/CeO2-P) showed significantly higher reactivity. More than 99.9% of ethylene conversion induced by Pt/CeO2-P could be sustained longer than 50 h at 25 °C, and 30 min even at 0 °C. Thus, Pt/CeO2 interface engineering by plasma modification technology is particularly promising for low-temperature catalytic oxidation of ethylene. Moreover, a comprehensive characterization was conducted to elucidate the reaction pathway and oxidation mechanism. From the preservation test using bananas as fruit samples, it was found that Pt/CeO2-P delayed postharvest deterioration and ripening of bananas due to the excellent ethylene scavenging effect created by the catalyst, thus demonstrating the great potential applications in F&V preservation.

Biological and postharvest interventions to manage the ethylene in fruit: a review

“…Several metals such as Pt, Au, Ag and Ti have been used by researchers. 73 Moreover, Wei et al 95 found that Pt/CeO 2 –O showed the highest low temperature C 2 H 4 catalytic oxidation activity. In a separate study, it was noticed that CeO 2 -octahedron-supported Pt catalysts could be a better tool for catalytic oxidation of ethylene at low temperature.…”

“…In a separate study, it was noticed that CeO 2 -octahedron-supported Pt catalysts could be a better tool for catalytic oxidation of ethylene at low temperature. Wei et al 95 observed that a Pt/plasma-modified CeO 2 catalyst (Pt/CeO 2 -P) exhibited significantly higher catalytic reactivity of ethylene oxidation at low temperature compared to Pt/pristine CeO 2 .…”

Construction of cerium-based oxide catalysts with abundant defects/vacancies and their application to catalytic elimination of air pollutants

“…These interactions optimized the surface chemical states, promoted the formation of surface oxygen vacancies, activated the surface oxygen species, and improved the low-temperature reducibility. Wei et al 167 synthesized CeO 2 -octahedron-supported Pt catalysts and then modified them by capacitively coupled plasma to achieve efficient catalytic oxidation of C 2 H 4 . After the plasma treatment, CeO 2 with rich oxygen vacancies was created, which acted as the support to facilitate the regulation of the size and dispersion of Pt nanoparticles.…”