2024
DOI: 10.1021/acs.est.4c05967
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Surface Nitrate Enrichment and Enhanced HONO Production from Ionic Surfactant Aggregation at the Aqueous-Air Interface

Qiong Li,
Shuaishuai Ma,
Qiuyue Ge
et al.

Abstract: Significant discrepancies persist between field observations and model simulations regarding the strength of marine-derived HONO sources, underscoring the urgency to resolve unidentified HONO sources. In this study, sodium dodecyl sulfate (SDS) was chosen as a proxy for marine surfactants to investigate its impact on aqueous nitrate photolysis for the first time. Remarkable increases in HONO and NO 2 production rates by factors of 3.3 and 5.6, respectively, along with a 1.9-fold rise in NO 2 − concentration, w… Show more

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