Wire drawing is the most widely employed process for manufacturing the micrometer sized gold wire (φ10 − φ50 µm) used for electronic interconnects. Currently, gold wire is applied in the bonding pad and miniaturization has resulted in need of higher quality of wire; wire quality is dependent on mechanical properties. The mechanical properties are based on microstructural behavior. This work was performed during my Ph.D candidature at Nanyang Technological University, Singapore. This thesis would not have been possible without the cooperation and time of many people, whom I owe my deepest gratitude to. • My greatest thanks are reserved for my supervisor Associate Professor Sridhar Idapalapati whose help shall remain understated. His enthusiasm, inspiration and encouragement rubs off on students motivating us to perform better. His sound advice, constructive criticisms and his ability to explain things in a lucid manner shall always be remembered. • I would also like to thank Assistant Professor Sathyan Subbiah for co-advising this thesis. His efforts in guiding the thesis was amazing. It was an exorbitant privilege working with him. • My committee members Associate Professors Liu Er Jia, Tang Ming Jen and Assistant Professor Castagne Sylvie for overlooking my thesis work. • My special thanks to our subject librarian Mr. Ramaravikumar Ramakrishnan for providing me all the necessary resources for doing this Ph.D research. The library walk thru and ENDNOTE workshops were extremely helpful. His affable and risible attitude will always be remembered. • Thanks to Ms. Yong Mei Yoke for helping me with the SEM, Mr. Leong Kwok Phui for assisting me with the XRD and Dr. Zviad of the MSE school with the pole figure measurements. Mr. Teo Hai Beng for setting my LINUX cluster without which my simulations would never have happened.