Surface passivation of nylon-6,6 films by graft copolymerization for reduction of moisture sorption

Abstract

To improve the moisture sorption property of nylon‐6,6 film, ally pentafluorobenzene (APFB) was incorporated on the argon plasma‐pretreated nylon film by UV or thermally induced surface graft copolymerzation. The plasma pretreatment introduced peroxides that were degraded into radicals to initiate the graft copolymerization of APFB on the nylon surface. The modified surfaces were characterized by X‐ray photoelectron spectroscopy (XPS) and contact angle measurement. The moisture sorption was assessed by the coulometric test method. The efficiency of surface graft copolymerization was affected by plasma pretreatment time of the nylon substrate, as well as by the UV or thermal graft copolymerization time. The UV graft‐copolymerized nylon film exhibited a significantly lower extent of moisture sorption when compared to that of the pristine films, even at low graft concentration. However, the moisture sorption behavior for the thermally graft copolymerized films was similar to that of the pristine films. Contact angle and XPS measurements suggested that the reduction in moisture sorption for the UV graft‐copolymerized nylon‐6,6 film was attributable to the fact that the hydrophobic polymer layer was formed on the nylon surface, and the hydrophobic layer of an appropriate thickness could serve as an effective barrier to moisture. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 1366–1373, 2000

Fluorinated Oligomers and Polymers in Photopolymerization

“…Employing fluoromonomers makes the substrate hydrophobic, oleophobic, antifouling, etc. Examples include cellulosic substrates like cotton , and paper, , and synthetic fibers . Moreover, photografting of fluoromonomers is also reported for modifying particles such as graphene, , or polymeric patterns, hence generating micro- and nanoscale hierarchical structures …”

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