We
present a simple and economically convenient method to fabricate
nanopatterned ZnO films by imprinting lithography and use them for
the layer alignment of liquid crystal (LC) displays. First, a one-dimensional
nanopattern was obtained by laser interference lithography on a silicon
wafer, and the silicon mold replica was transferred onto a flexible
polydimethylsiloxane (PDMS) sheet for conformal patterning. The so-obtained
PDMS mold was then applied on a ZnO film spin-coated on a glass substrate.
During the imprinting process, the temperature was controlled from
100 to 250 °C to observe the transferring morphologies of the
ZnO film; the nanopattern was successfully transferred at annealing
temperatures of 200 and 250 °C because the ZnO film at the sol
state filled the cavities of the PDMS nanopattern and solidified,
forming a negative replica of the nanopattern. The direction of the
nanopatterned ZnO film served as a guide for aligning the LC molecules
on the LC surface at the centimeter scale and, due to their elastic
characteristics and group behavior, propagating their directional
states in the LC bulk. The resulting LC cell exhibited an enhanced
electro-optical performance and high thermal endurance above 180 °C.
The geometry of the alignment layer increased the electric field on
the ZnO film and showed reduced threshold voltage. In addition, since
flexible devices are generally based on polyimide, which imidized
at around 200 °C, the relatively low annealing temperatures of
our fabricated nanopatterned ZnO film allow it to be mounted on such
devices without any deterioration of the underlying thermoplastic
substrate. Therefore, nanopatterned ZnO has a considerable potential
for advanced LC displays.