Complex formation behavior between phenols and alkanes containing two pyrrolidone moieties at both termini [l,n-bis[l-(2-oxopyrrolidin)yl]alkanes(l,n-DP As)], as model compounds of polymers carrying an amide group in the side chain, was investigated by means of NMR, IR, and UV. In the IR study, a frequency decrease of the carbonyl absorption of l,n-DPAs upon addition of phenol was observed, which was suggested to result from hydrogen bonding. The frequency change occurred independent of the methylene chain length and the presence of solvent but its magnitude depended on the concentration.NMR chemical shifts of l,n-DPAs were clearly changed by addition of phenols. Most signals of l,n-DPAs shifted to higher field, while only signals of methylene protons adjacent to the carbonyl group shifted to lower field. Detailed NMR study using 1,3-DPA, phenols, and related compounds indicated that the interaction between l,n-DPAs and phenols could be attributed to the favorable formation of charge-transfer stacking (C-T stacking) as well as hydrogen bonding. Furthermore, the strength of the interaction between l,n-DPAs and phenols was affected by the para substituents of the phenols and the polarity of the solvents. UV study demonstrated that l,n-DPAs formed 1:2 complexes with phenol (pyrrolidone group:phenol = 1:1). The driving force of the complex formation is believed to be due not only to hydrogen bonding but also to C-T stacking.