The Brazilian agro-industrial chain generates about 291 million/tons/year of wastes, which, if inadequately destinated, could originate social and environmental risks. There is a growing need for the use of alternative raw materials to replace that originated from fossil resources in the Brazilian industry. Renewable materials play an important role on the sustainability of ecosystems and materials’ circularity. The issue has acquired importance in light of recent bio-based agro-fiber development potential applications. Considering sustainability guidelines, this study aimed to analyze the main Brazilian agro-industrial waste crops (temporary and permanent) as important sources of natural fibers and other raw materials. A systematic review of the literature (SRL) about Brazilian researches, based on concepts of industrial ecology, and the creation of a bibliometric analysis network were carried out. The agricultural biomass related to the main crops presents characteristics making them suitable to be applied for textiles, as natural fibers and polymers, in biosorbents for industrial effluents, and cellulose obtention and reinforcement material in composites. Thus, scientific investment in researches on materials and technology development are necessary to provide applications that could meet current and future demands and expand the scope of new materials for sustainability.