Sustainable and Green Approach for Api 5L Pipeline Steel Acidic Corrosion Inhibition Using Agro-Industrial Waste: Experimental and Theoretical

Abstract

Currently, the use of synthetic inhibitors in preventing corrosion is destructive to the environment; therefore, natural inhibitors might be an alternative and innovative solution to this challenge, owing to their sustainability. Herein, wasted avocado seed extract was examined as a sustainable and green inhibitor for API 5L X65 pipeline steel at an ambient temperature using the gravimetric analysis, the potentiodynamic polarization curve, and linear polarization resistance techniques. The inhibitor’s chemical characterization was carried out with Fourier-transform infrared spectroscopy (FTIR), and the morphological characterization was carried out by detailed scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM/EDX). The result showed that the extract decreased the corrosion rate by retarding the cathodic and anodic electrochemical reactions, with a maximum efficiency of 88% at 5 g/L. The extract was adsorbed physically onto the X 65 steel following the Langmuir adsorption isotherms. The electrochemical studies showed that the agro-waste was a mixed-type inhibitor. The SEM image of the X65 steel with the extract showed thin film formation on the steel surface. The extract can be substituted for synthetic inhibitors, which are toxic, scarce, and costly.

Novel high-performance and cost-effective green inhibitor based on fundamental theoretical evaluations combined with electrochemical/surface examinations of Arachis hypogaea shell extract for pipeline steel corrosion in 1 M H2SO4 solution

“…In this study, from the gravimetric test with 4 g/L Arachis hypogaea shell extract, 98.42% efficiency was derived. This efficiency is greater than most of the reported green inhibitors [24][25][26][27]. The process of extracting most inhibitors with efficiency lower than Arachis hypogaea shell extracts are expensive.…”

“…Popoola et al investigated the influence of avocado seed extracts on the corrosion of API X 65 pipeline steel in 1 M H 2 SO 4 solutions and found 88% efficiency with 5 g L −1 inhibitor [24]. Amal A Altalhi showed that diazenebased Schiff base derivatives showed 90.4 and 92.6% efficiency on API stainless steel at 100 ppm concentration [25].…”