The synthesis of the carbon–hydrogen–oxygen
symbiosis
network (CHOSYN) provides a structured framework for dealing with
multiscale integration of hydrocarbon processing industries to improve
resource efficiency and reduce waste generation. However, the earlier
CHOSYN design approaches presumed that the networks operate in a single
mode throughout the year. This may not be the case in real-world situations
where the production of certain plants such as polyhydroxyalkanoates
(PHAs) from bio-based glycerol may require multiple operational modes
to accommodate the seasonal variability and availability of raw material.
PHAs are biodegradable polymers produced by bacterial fermentation
of carbon sources, which are the potential substitutions for petrochemical-based
plastics. Hence, this work aims to propose a systematic approach to
optimize multiperiod mass integration in the development of a CHOSYN.
The central principle of the proposed approach is the incorporation
of a storage and dispatch system into the conventional CHOSYN design
for the supply of chemical species needed in the network throughout
different operational periods. A case study considering glycerol valorization
and other chemical plants using the devised CHOSYN model was conducted
to evaluate the performance of the proposed design against the conventional
CHOSYN in terms of sustainability metrics. The results demonstrate
the advantages of the CHOSYN model with a storage and dispatch system
by exhibiting a better profitability outcome than the conventional
multiperiod CHOSYN through operating cost savings.