Sustainable chemistry approach for the preparation of bluish green emissive copper nanoclusters fromJusticia adhatodaleaves extract: a facile analytical approach for the sensing of myoglobin andl-thyroxine
“…To overcome these drawbacks, many small molecular substances especially amino acids such as histidine, 27 tyrosine, 28 proline, 29 cysteine, [30][31][32] methionine 33,34 were selected. Phytochemicals containing natural proteins and biomolecules such as Justicia adhatoda leaves 35 and curcuma roots 36 were proven as the template for the synthesis of nanoclusters. 2-Mercaptopyrimidine as a surface ligand was reported in Shraddha Borse's work.…”
“…To overcome these drawbacks, many small molecular substances especially amino acids such as histidine, 27 tyrosine, 28 proline, 29 cysteine, [30][31][32] methionine 33,34 were selected. Phytochemicals containing natural proteins and biomolecules such as Justicia adhatoda leaves 35 and curcuma roots 36 were proven as the template for the synthesis of nanoclusters. 2-Mercaptopyrimidine as a surface ligand was reported in Shraddha Borse's work.…”
“…24 Above all, CuNCs are particularly appealing due to their simple, one-step fabrication approach that doesn't require any hazardous solvents. 25…”
Section: Introductionmentioning
confidence: 99%
“…24 Above all, CuNCs are particularly appealing due to their simple, one-step fabrication approach that doesn't require any hazardous solvents. 25 In this perspective, the present work is done to address the dual and sensitive detection of OH and PPi by a ''turn-off-on'' mechanism using trypsin-mediated synthesis of coffee-CuNCs. Fluorescence, UV-visible absorption, X-ray photoelectron spectroscopic (XPS) and Fourier transform infrared (FT-IR) technologies have been used for the investigation of the sensing activity of coffee-Tryp-CuNCs in the presence and absence of the analytes.…”
In the present work, an off-on fluorescent probe based on green light-emitting coffee-trypsin-CuNCs (Coffee-Tryp-CuNCs) is developed for the quick, accurate, and targeted detection of •OH and pyrophosphate ion (P2O74–, PPi)....
“…The researchers are constantly looking for a low-or nontoxic eco-friendly substance to synthesize Cu NCs with quantitative and qualitative properties. 38 In this regard, the native plant "painted neetle" Plectranthus scutellarioides (P. scutellarioides) having purplish leaves, widely grown in India as an ornamental plant and as a medicinal herb in Indonesia was chosen as a biological ligand. 39 This plant is easily accessible, widely propagated, and can be disposed of as a biowaste.…”
The development of superior sensors that can detect terbufos insecticide in the fields of agriculture and human health is of utmost importance. Herein, green emissive copper nanoclusters (Cu NCs) were fabricated using the extract of Plectranthus scutellarioides (P. scutellarioides) leaves as biological ligands. The synthesized Plectranthus scutellarioides-Cu NCs (P. scutellarioides-Cu NCs) possess green fluorescence (FL) under UV-light and depict excitation-dependent emission behavior at 450 nm showing maximum emission intensity at 510 nm. The dispersive nature and size of the P. scutellarioides-Cu NCs were calculated to be 2.1 ± 0.6 nm using high-resolution transmission electron microscopy (HR-TEM). The as-synthesized P. scutellarioides-Cu NCs are waterdispersive and show good stability. The introduction of terbufos quenched the FL intensity of P. scutellarioides-Cu NCs via a static quenching mechanism. With terbufos concentrations ranging from 0.1 to 4.0 μM, the ratio of I 0 /I of P. scutellarioides-Cu NCs showed a clear linear relationship with a corresponding low detection limit (LOD) of 0.029 μM. The as-synthesized detection methodology was successfully used to analyze terbufos in vegetable (carrot) and water samples with good recovery and relative standard deviation (RSD) values of less than 2. The real-time study was also performed using a paper-strip-based detection method.
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