Sustainable metal-organic framework co-engineered glass fiber separators for safer and longer cycle life of Li-S batteries

Ponnada, Srikanth; Mansoor, Mubashir; Aslfattahi, Navid; Baydoğan, Nilgün; Naskar, Susmita; Sharma, Rakesh K.; Kiai, Maryam Sadat

doi:10.1016/j.jallcom.2023.168962

Cited by 10 publications

(7 citation statements)

References 41 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Similarly, the sulfur and lithium adsorption sites can show a plethora of different configurations, as adsorption energies depend on the local chemical potential equilibria. This means, by bringing together different combinations of phases in conjuncture with the 2D heterostructure, the S and Li adsorption sites can be manipulated as well, to the advantage, as it was shown in our earlier study . One example that is of particular interest by Grixti et al, that shows the use of 2D boron for the adsorption of polysulfides, that can reduce the shuttling effect.…”

Section: Dft and Mechanism Analysis For 2d Materials (Heterostructures)mentioning

confidence: 71%

“…This means, by bringing together different combinations of phases in conjuncture with the 2D heterostructure, the S and Li adsorption sites can be manipulated as well, to the advantage, as it was shown in our earlier study. 146 One example that is of particular interest by Grixti et al, 147 that shows the use of 2D boron for the adsorption of polysulfides, that can reduce the shuttling effect. Their use of charge density difference and calculation of binding energies can be adopted to a plethora of other 2D materials as well, which can accelerate the progress in Li−S batteries without shuttling effects.…”

Section: Dft and Mechanism Analysis For 2d Materials (Heterostructures)mentioning

confidence: 99%

See 1 more Smart Citation

Synergistic Overview and Perspectives of Two-Dimensional Heterostructures for Cathodes and Separators in Flexible Li–S Batteries

et al. 2023

Self Cite

View full text Add to dashboard Cite

Because of their high energy densities and specific capacities, lithium–sulfur (Li–S) batteries have recently received an extensive amount of research. The best way to boost battery performance is by altering the electrode materials. The adoption of 2D material-based heterostructures has attracted significant attention for increasing electrochemical performance and preventing the shuttle effect. Therefore, a summary of the link between the specific properties of 2D material heterostructures and electrochemical performance is required for the development of next-generation Li–S batteries. The present research focuses on the latest developments that boost the performance of Li–S batteries by using the unique features of 2D material heterostructures. This evaluation also categorizes several meticulously selected 2D materials with specific properties. Some solutions have been developed to overcome the difficulties of insulating intermediates, polysulfide shuttle, and sluggish kinetics. Superior conductivity, tunable functional groups, and exceptional flexibility are some of the most crucial elements in boosting electrochemical performance.

show abstract

Section: Dft and Mechanism Analysis For 2d Materials (Heterostructures)mentioning

confidence: 71%

Section: Dft and Mechanism Analysis For 2d Materials (Heterostructures)mentioning

confidence: 99%

Synergistic Overview and Perspectives of Two-Dimensional Heterostructures for Cathodes and Separators in Flexible Li–S Batteries

et al. 2023

Self Cite

View full text Add to dashboard Cite

show abstract

“…Ponnada and co‐workers have demonstrated the effects of pore size and chemical affinity of Cu/MOF and Fe/MOF on the inhibition of polysulfides. [ 197 ] The unsaturated metal sites can chemically adsorb polysulfides even though the pore sizes of Fe/MOF and Cu/MOF are much larger than those of polysulfides, thereby restraining the shuttling of polysulfides, especially long‐chain dissolvable polysulfides.…”

Section: Size Effect In Separatorsmentioning

confidence: 99%

Size Effect for Inhibiting Polysulfides Shuttle in Lithium‐Sulfur Batteries

Kang,

He,

Zou

et al. 2023

Small

View full text Add to dashboard Cite

It is undeniable that the dissolution of polysulfides is beneficial in speeding up the conversion rate of sulfur in electrochemical reactions. But it also brings the bothersome “shuttle effect”. Therefore, if polysulfides can be retained on the cathode side, the efficient utilization of the polysulfides can be guaranteed to achieve the excellent performance of lithium‐sulfur batteries. Based on this idea, considerable methods have been developed to inhibit the shuttling of polysulfides. It is necessary to emphasize that no matter which method is used, the solvation mechanism, and existence forms of polysulfides are essential to analyze. Especially, it is important to clarify the sizes of different forms of polysulfides when using the size effect to inhibit the shuttling of polysulfides. In this review, a comprehensive summary and in‐depth discussion of the solvation mechanism, the existing forms of polysulfides, and the influencing factors affecting polysulfides species are presented. Meanwhile, the size of diverse polysulfide species is sorted out for the first time. Depending on the size of polysulfides, tactics of using size effect in cathode, separator, and interlayer parts are elaborated. Finally, a design idea of materials pore size is proposed to satisfy the use of size effect to inhibit polysulfides shuttle.

show abstract

“…The addition of some functional groups, such as oxides, hydroxides, and fluo-rine, can enhance polarity and restrain the dissolution of polysulfides. [13][14][15] Researchers have used a structure-oriented technique to increase lithium polysulphides' redox kinetics by decorating tungsten phosphide (WP) nanocrystals on N,P codoped carbon sheets (WP/NPC) with uniform dispersion in Li-S batteries. 47 The lithium anode, CoTeNCGs (CoTe nitrogendoped nanotubes and graphene-like carbon) with outstanding lithiophilic properties, efficiently manages the uniform deposition of lithium and restricts the chaotic formation of lithium dendrites.…”

Section: Introductionmentioning

confidence: 99%

Ti₃C₂T_x nanosheet@Cu/Fe-MOF separators for high-performance lithium–sulfur batteries: an experimental and density functional theory study

Kiai,

Ponnada,

Eroglu

et al. 2024

Dalton Trans.

Self Cite

View full text Add to dashboard Cite

show abstract

Sustainable metal-organic framework co-engineered glass fiber separators for safer and longer cycle life of Li-S batteries

Cited by 10 publications

References 41 publications

Synergistic Overview and Perspectives of Two-Dimensional Heterostructures for Cathodes and Separators in Flexible Li–S Batteries

Synergistic Overview and Perspectives of Two-Dimensional Heterostructures for Cathodes and Separators in Flexible Li–S Batteries

Size Effect for Inhibiting Polysulfides Shuttle in Lithium‐Sulfur Batteries

Ti₃C₂T_x nanosheet@Cu/Fe-MOF separators for high-performance lithium–sulfur batteries: an experimental and density functional theory study

Contact Info

Product

Resources

About

Sustainable metal-organic framework co-engineered glass fiber separators for safer and longer cycle life of Li-S batteries

Cited by 10 publications

References 41 publications

Synergistic Overview and Perspectives of Two-Dimensional Heterostructures for Cathodes and Separators in Flexible Li–S Batteries

Synergistic Overview and Perspectives of Two-Dimensional Heterostructures for Cathodes and Separators in Flexible Li–S Batteries

Size Effect for Inhibiting Polysulfides Shuttle in Lithium‐Sulfur Batteries

Ti3C2Tx nanosheet@Cu/Fe-MOF separators for high-performance lithium–sulfur batteries: an experimental and density functional theory study

Contact Info

Product

Resources

About

Ti₃C₂T_x nanosheet@Cu/Fe-MOF separators for high-performance lithium–sulfur batteries: an experimental and density functional theory study