To address the effect of a ship’s rolling on the fluidization quality of fluidized beds, in this study, a simulation of a rolling fluidized bed with longitudinal internal members added (R-FBLIM) was carried out and compared with that of a rolling fluidized bed without internal members added (R-FBWIM). The transient motion, as well as the behavioral characteristics of the bubbles within the R-FBLIM, was analyzed; the variation patterns of the number of bubbles, as well as the equivalent diameter of the bubbles, were compared for different apparent gas velocities, oscillation periods, and amplitudes; and the mechanism of the action of the longitudinal internal members was investigated. The results show that the structural design of the longitudinal internal members can effectively improve the gas–solid fluidization quality of the rolling fluidized bed. The horizontal support plate and the cap hole structure can effectively break the air bubbles, the cap hole structure promotes the radial mixing of the gas–solid fluid, and the internal and outer rings of the curved surface plate roll in rows, which inhibit the aggregation behavior of the gas–solid fluid to the two sides of the oscillating planes, respectively, by cooperating with the cap hole structure. Compared with R-FBWIM, the gas–solid phase within R-FBLIM is more spatially distributed, with the number of bubbles increasing by about 2–4 times and the mean diameter decreasing by about 50–60%. The number of bubbles increases with the gas velocity but decreases with the rolling amplitude; the mean diameter decreases with the gas velocity but responds less to the rolling amplitude change.