The rollout of electric vehicles and photovoltaic panels is essential to mitigate climate change. However, they depend on technology‐critical elements (TCEs), which can be harmful to human health and whose use is rapidly expanding, while recycling is lacking. While mining has received substantial attention, in‐use dissipation in urban areas has so far not been assessed, for example, corrosion and abrasion of vehicle components and weather‐related effects affecting thin‐film photovoltaic panels. Therefore, the question arises to which extent TCEs dissipate during use and which potential non‐occupational human health impacts could occur. We assessed the available information on urban in‐use dissipation and human health concerns and conducted exploratory modeling of in‐use technology stocks, in‐ and outflows, and in‐use dissipation of neodymium, dysprosium, lanthanum, praseodymium, cerium, gallium, germanium, and tellurium contained in 21 vehicle and renewable energy technologies, for Vienna, Austria. In prospective scenarios, TCE dynamics in a trend‐continuation vis à vis official city policy plans and a more ambitious transition scenario were then assessed. We find that electrifying the vehicle fleet without demand‐reduction is the main driver of TCE consumption, effectively doubling cumulative end‐of‐life outflows to 3,073 [2,452–3,966] t and cumulative in‐use dissipation to 9.3 [5.2–15.7] t by the year 2060. Sufficiency‐based measures could reduce demand and in‐use dissipation well below levels with continued trends, thus highlighting the need to combine decarbonization with demand‐reducing measures. These results help assess potential future in‐use dissipation dynamics and inform discussions about potential public health hazards associated with exposure to TCEs accumulating in the urban environment.