The iron and steel industry is a pillar industry of the national economy in many countries and is also a source of high energy consumption and pollution gas emissions. In addition to the economic aspect, there have been increasing concerns over how to minimise the negative environmental impact and enhance the awareness of social responsibility for iron and steel enterprises. Therefore, this study proposes an intelligent scheduling system for addressing the supplier selection problem by considering sustainable scheduling (SS) (ISS-AFLCSS) to achieve maximised benefits of logistics costs, carbon emission and fatigued driving for the Chengsteel Company. In the ISS-AFLCSS, first, a multiobjective mathematical optimisation model is formulated. Second, this study proposed a hybrid approach using an improved genetic algorithm (GA) to optimise multiple objectives of scenarios and adopting the technique for order preference by similarity to an ideal solution (TOPSIS) method with the analytic hierarchy process (AHP) to precisely optimise and select a best-ideal scenario. The results confirm that the proposed ISS-AFLCSS can provide accurate guidance in practicing SS for managers of enterprises.