Sustainable synthesis of fluorescent polymer carbon dots@PVA for sensitive chlortetracycline detection

Abstract

Antibiotic residues persist in the environment and represent serious health hazards; thus, it is important to develop sensitive and effective detection techniques. This paper presents a bio‐inspired way to make water‐soluble fluorescent polymer carbon dots (PCDs@PVA) by heating biomass precursors and polyvinyl alcohol (PVA) together. For example, the synthesized PCDs@PVA are very stable with enhanced emission intensity. This property was observed in a wide range of environmental conditions, including those with changing temperatures, pH levels, UV light, and ionic strength. PCDs@PVA detected the antibiotic chlortetracycline (CTCs) with great selectivity against structurally related compounds and a low detection limit of 20 nM, demonstrating outstanding sensitivity and specificity. We confirmed the sensor's practical application through real sample analysis, yielding recovery rates of 98%–99% in samples of milk, honey, and river water. The synthesized PCDs@PVA fluorescence sensor was successfully used for CTCs detection in real samples.