Sustenance of hydrogen–oxygen cellular detonation with ozone additions in confined space

Abstract

The sustenance of cellular detonation under weak confinement is studied through two-dimensional (2D) numerical simulations of hydrogen–oxygen mixtures surrounded by inert gas. The results show that in the weakly confined space, the cellular detonation with Chapman-Jouguet velocity can survive by increasing the width of the reactant layer and enhancing the reactivity of reactants, which ensures enough triple points and high reactivity in the reactant layer for detonation sustenance since transverse shocks cannot be regenerated and reinforced by boundary reflection. By adding ozone into the system and changing the width of the reactant layer, the relationship between induction length and detonation sustenance is established. It is found that the sustenance of cellular detonation in the weakly confined space is related to the ratio of the reactant layer width to the induction length. Ozone reactions can reduce the induction length and enhance reactivity, thereby promoting the generation of new transverse shocks and significantly improving the sustenance of cellular detonation in weakly confined space.