2024
DOI: 10.1039/d4qo00392f
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Switching from gem-difluorovinylation to carboxylation: ligand-enabled palladium-catalyzed Heck annulation of alkene-tethered aryl halides with sodium difluorochloroacetate

Yu Xia,
Wenqi Li,
Minzhu Wei
et al.

Abstract: Reported herein is the use of ligand to tune palladium-catalyzed intramolecular Heck gem-difluorovinylation and carboxylation with alkene-tethered aryl halides, which provides an efficient avenue for building indolo[2,1-a]isoquinoline skeletons. The sodium...

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