1969
DOI: 10.1016/s0022-328x(00)85407-8
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Symmetrisierung unsymmetrisch substituierter organometallsulfide von germanium, zinn und blei

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Cited by 6 publications
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“…Seeking to prepare heteroleptic tin phosphides to serve as potential single-source precursors to indium phosphide materials, we turned to the reported indium monoiodide (XL) 2 InI, which we expected to give rise to a molecule with a 1:1 ratio of In/P. Additionally, its thiolate XL units will potentially be removable subsequently as Ph 3 SnXL . The indium phosphide (XL) 2 InP(SnPh 3 ) 2 was obtained in 84% isolated yield as a monomeric species (see Scheme ).…”
Section: Resultsmentioning
confidence: 99%
“…Seeking to prepare heteroleptic tin phosphides to serve as potential single-source precursors to indium phosphide materials, we turned to the reported indium monoiodide (XL) 2 InI, which we expected to give rise to a molecule with a 1:1 ratio of In/P. Additionally, its thiolate XL units will potentially be removable subsequently as Ph 3 SnXL . The indium phosphide (XL) 2 InP(SnPh 3 ) 2 was obtained in 84% isolated yield as a monomeric species (see Scheme ).…”
Section: Resultsmentioning
confidence: 99%
“…47 The non-symmetrical aliphatic derivatives R 1 3 E 1 TeE 2 R 2 3 easily disproportionate to give the symmetrical tellurides (R 1 3 E 1 ) 2 Te and (R 2 3 E 2 ) 2 Te. 70 The Te7E bonds in tellurides 7 are easily cleaved under the action of various oxidants. Thus the silyl derivatives 7h,i react with oxygen to give elementary tellurium and the corresponding siloxane.…”
Section: Reactions Of Compounds (R 3 E) 2 Tementioning
confidence: 99%