In this paper, two different nonlinear coupled Markovian switching delayed network models with multiple weights are established, and the effects of parameter and model uncertainties and external disturbances are fully considered. Firstly, based on the finite-time theory, several sufficient conditions for the finite-time synchronization of Markovian switching networks are obtained. Secondly, under the feedback controller with adaptive laws, when the synchronization of the networks is achieved in a finite time, the uncertain parameters of the networks can also be identified as true values. Finally, a representative numerical simulation is given to further illustrate the validity and practicability of the theoretical analysis and proof of this paper.