Abstract. Earth's long-term cycling of carbon is regulated from
mid-ocean ridges to convergent plate boundaries by mass transfers involving
mantle rocks. Here we examine the conversion of peridotite to listvenite
(magnesite + quartz rock) during CO2 metasomatism along the basal
thrust of the Semail Ophiolite (Fanja, Sultanate of Oman). At the outcrop
scale, this transformation defines reaction zones, from serpentinized
peridotites to carbonated serpentinites and listvenites. Based on a
detailed petrological and chemical study, we show that carbonation
progressed through three main stages involving the development of replacive
textures ascribed to early stages, whilst carbonate (± quartz) veining
becomes predominant in the last stage. The pervasive replacement of
serpentine by magnesite is characterized by the formation of spheroids,
among which two types are identified based on the composition of their core
regions: Fe-core and Mg-core spheroids. Fe zoning is a type feature of
matrix and vein magnesite formed during the onset carbonation (Stage 1).
While Fe-rich magnesite is predicted to form at low fluid XCO2 from a
poorly to moderately oxidized protolith, our study evidences that the local
non-redox destabilization of Fe oxides into Fe-rich magnesite is essential to
the development of Fe-core spheroids. The formation of Fe-core spheroids is
followed by the pervasive (over-)growth of Mg-rich spheroids and aggregates
(Stage 2) at near-equilibrium conditions in response to increasing fluid
XCO2. Furthermore, the compositions of carbonates indicate that most
siderophile transition elements released by the dissolution of primary
minerals are locally trapped in carbonate and oxides during matrix
carbonation, while elements with a chalcophile affinity are the most likely
to be leached out of reaction zones.