“…Such a large exciton binding energy allows stable existence of excitons and efficient excitonic emission at RT. Different growth methods, including pulsed laser deposition (PLD), , molecular beam epitaxy (MBE), , atomic layer deposition (ALD), , metal–organic chemical vapor deposition (MOCVD), , and vapor phase epitaxy (VPE) have been employed to grow ZnO films. Besides the most commonly adopted substrate, sapphire, other substrates or buffer layers with small lattice mismatch, such as γ-LiAlO 2, ScAlMgO 4 , and GaN − have been adopted to grow high-quality ZnO with low defect densities.…”