Synergistic Activation of Nitrite and Thiocarbonyl Compounds Affords NO and Sulfane Sulfur via (Per)thionitrite (SNO−/SSNO−)
Gayathri Kolliyedath,
Tuhin Sahana,
Silpa Mary Johnson
et al.
Abstract:(Per)thionitrite (SNO–/SSNO–) intermediates play vital roles in modulating nitric oxide (NO) and hydrogen sulfide (H2S) dependent bio‐signalling processes. Whilst the previous preparations of such intermediates involved reactive H2S/HS– or sulfane sulfur (S0) species, the present report reveals that relatively stable thiocarbonyl compounds (such as carbon disulfide (CS2), thiocarbamate, thioacetic acid, and thioacetate) react with nitrite anion to yield SNO–/SSNO–. For instance, the reaction of CS2 and nitrite… Show more
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