Synergistic Effect of Dual-Ceramics for Improving the Dispersion Stability and Coating Quality of Aqueous Ceramic Coating Slurries for Polyethylene Separators in Li Secondary Batteries

Abstract

We demonstrate that dispersion stability and excellent coating quality are achieved in polyethylene (PE) separators by premixing heterogeneous ceramics such as silica (SiO2) and alumina (Al2O3) in an aqueous solution, without the need for functional additives such as dispersing agents and surfactants. Due to the opposite polarities of the zeta potentials of SiO2 and Al2O3, SiO2 forms a sheath around the Al2O3 surface. Electrostatic repulsion occurs between the Al2O3 particles encapsulated in SiO2 to improve the dispersion stability of the slurry. The CCSs fabricated using a dual ceramic (SiO2 and Al2O3)-containing aqueous coating slurry, denoted as DC-CCSs, exhibit improved physical properties, such as a wetting property, electrolyte uptake, and ionic conductivity, compared to bare PE separators and CCSs coated with a single ceramic of Al2O3 (SC-CCSs). Consequently, DC-CCSs exhibit an improved electrochemical performance, in terms of rate capability and cycle performance. The half cells consisting of DC-CCSs retain 93.8% (97.12 mAh g−1) of the initial discharge capacity after 80 cycles, while the bare PE and SC-CCSs exhibit 22.5% and 26.6% capacity retention, respectively. The full cells consisting of DC-CCSs retain 90.9% (102.9 mAh g−1) of the initial discharge capacity after 400 cycles, while the bare PE and SC-CCS exhibit 64.7% and 73.4% capacity retention, respectively.

Thin, Highly Ionic Conductive, and Mechanically Robust Frame‐Based Solid Electrolyte Membrane for All‐Solid‐State Li Batteries

“…[37][38][39][40] Furthermore, PE separators have high chemical stability, even toward sulfide-based solid electrolytes. [40][41][42][43] These advantages have led to the utilization of thin PE separators as supporting frames for all-solid-state electrolyte membranes. However, when an SE layer is coated on both sides of the separator, which has only nanosized pores, facile Li-ion pathways cannot be formed with the SE particles of a few micrometers.…”