Synergistic effect of ultrathin thickness and surface oxygen vacancies in high-efficiency Ti-mediated Bi2MoO6 for immense photocatalytic nitrofurantoin degradation and Cr(VI) reduction

Simultaneous Pd Nanoparticle Deposition and Enhancement in the Surface Oxygen Vacancy of Bi2MoO6 Nanoflakes for Room Temperature Vanillin Hydrodeoxygenation

“…However, a significant decrease in the intensities of the peaks at 146, 194, 287, 348, 718, 799, and 844 cm –1 was observed for all Pd-supported samples. This decrease in intensity was probably due to increasing the surface oxygen vacancies (SOVs) induced due to the solid-state reaction of BMO with NaBH 4 during the loading of Pd nanoparticles. , The generation of SOVs in metal oxides by the NaBH 4 reduction method has previously been reported in the literature. , Also, BMO is well known to comprise SOVs . It is important to note here that for increasing the loading of Pd over a fixed amount of the BMO support, an increasing amount of NaBH 4 was used in this study (see the synthesis procedure for Pd/BMO).…”

“…This decrease in intensity was probably due to increasing the surface oxygen vacancies (SOVs) induced due to the solid-state reaction of BMO with NaBH 4 during the loading of Pd nanoparticles. 54,55 The generation of SOVs in metal oxides by the NaBH 4 reduction method has previously been reported in the literature. 56,57 Also, BMO is well known to comprise SOVs.…”

Boosting Photocatalytic Nitrogen Fixation via Nanoarchitectonics Using Oxygen Vacancy Regulation in W-Doped Bi2MoO6 Nanosheets

“…Nanoarchitectonics of oxygen vacancy-rich Bi 2 MoO 6 has been investigated for many photocatalytic applications like removal of pollutants from wastewater, CO 2 reduction, and N 2 fixation because of its promising potential. ,, In addition, doping of Bi 2 MoO 6 with various other elements like Fe, F, etc. and heterojunctions based Bi 2 MoO 6 photocatalytic systems have also been explored for various applications. − However, there are no reports on W-doped Bi 2 MoO 6 for photocatalytic nitrogen fixation to the best of our knowledge. The substitution of Mo with W can induce changes in the crystal structure and morphology because of the different atomic radii of Mo and W. These modifications in the crystal structure can change the optical response of the W-doped Bi 2 MoO 6 and, hence, can amplify the photocatalytic activity.…”

Luminescent and photocatalytic activity of NaGd(MoO4)2:Dy3+/Eu3+ and NaGd(WO4)2:Dy3+/Eu3+ nanorods for efficient sensing and degradation of the antibiotic drug, nitrofurantoin

“…36 Arif et al reported on Ti-doped Bi 2 MoO 6 nanosheets for the detoxification of NFT with 89.4% efficiency. 37 As essential inorganic materials, transition metal-based molybdates and tungstates (M = Ni, Mn, Co, Sr, Fe, Ba, Zn, Pb, Ca, Cu,Cd, etc.) have been developed and significantly employed in numerous fields, such as photocatalysis, optical fibers, lasers, scintillators, supercapacitors, Li-ion storage batteries, magnetic properties, electrochemical, photoluminescence and humidity sensors.…”