2005
DOI: 10.1016/j.corsci.2004.09.020
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Synergistic inhibition between tween 60 and NaCl on the corrosion of cold rolled steel in 0.5M sulfuric acid

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Cited by 180 publications
(59 citation statements)
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“…In an exothermic process, both physisorption and chemisorption can be distinguished by considering the absolute value of Δ ads . For physisorption process, Δ ads is lower, that is 40 kJ mol −1 , while that for chemisorption approaches 100 kJ mol −1 [29]. In the present case Δ ads is 58.87 kJ mol −1 , which is an intermediate case clearly specifies the existence of both physical and chemical adsorption.…”
Section: Thermodynamic Parameters Of the Adsorption Isothermmentioning
confidence: 73%
“…In an exothermic process, both physisorption and chemisorption can be distinguished by considering the absolute value of Δ ads . For physisorption process, Δ ads is lower, that is 40 kJ mol −1 , while that for chemisorption approaches 100 kJ mol −1 [29]. In the present case Δ ads is 58.87 kJ mol −1 , which is an intermediate case clearly specifies the existence of both physical and chemical adsorption.…”
Section: Thermodynamic Parameters Of the Adsorption Isothermmentioning
confidence: 73%
“…Before starting the experiment, the working electrode with an area of 1 cm 2 was treated as in WL experiments and then immersed in a test solution for 30 min until a steady-state open circuit potential (OCP) was attained. The Stern-Geary method (21) used for the determination of corrosion current is performed by extrapolation of anodic and cathodic Tafel lines to a point which gives log i corr and the corresponding corrosion potential (E corr ) for inhibitor free acid and for each dose of drug. All experiments were carried out three times for reproducibility and all measurements were conducted at 25°C.ll measurements were conducted at 25C EIS was carried out at OCP in the frequency range 10 5 -10 −1 Hz, and the AC signal was 0.005 V in amplitude.…”
Section: Electrochemical Measurementsmentioning
confidence: 99%
“…Tafel polarization curves were determined by polarizing to ± 250 mV with respect to the free corrosion potential (E vs. SCE) at a scan rate of 0.5 mV/s. Stern-Geary method [14] used for the determination of corrosion current is performed by extrapolation of anodic and cathodic Tafel lines to a point which gives log i corr and the corresponding corrosion potential (E corr ) for inhibitor free acid and for each dose of inhibitor. Then i corr was used for calculation of inhibition efficiency (% IE) and surface coverage (θ) as in equation 2:…”
Section: Electrochemical Measurementmentioning
confidence: 99%