Synthese phosphat-verbrückter d-glucose-einheiten als teilstrukturen phosphorylierter stärken

Franzkowiak, Monika; Thiem, Joachim; Demoulin, Corinna

doi:10.1016/0008-6215(86)84003-4

Cited by 7 publications

(1 citation statement)

References 37 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…A few other G2P derivatives, namely the phosphodiester connecting two glucoses at O-2 and O-6, and a phenyl glucoside derivative were reported. [13][14][15] The quite rare D-glucose-2-phosphate, which we will refer to as G2P in this paper, is known since the late 1940's from the work by Fleury et al and by Farrar, 16,17 and has been observed as a product of the opening of the cyclic glucose-1,2-phosphate (GCP). 18 G2P was included in several studies on phosphate hydrolysis rates and phosphatases characterizations, 19 and used for analytical purposes for assessing starch or glycogen phosphorylation positions.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of a non-natural glucose-2-phosphate ester able to dupe the acc system of Agrobacterium fabrum

Vigouroux

Ahmar

et al. 2019

Org. Biomol. Chem.

View full text Add to dashboard Cite

show abstract

Section: Introductionmentioning

confidence: 99%

Synthesis of a non-natural glucose-2-phosphate ester able to dupe the acc system of Agrobacterium fabrum

Vigouroux

Ahmar

et al. 2019

Org. Biomol. Chem.

View full text Add to dashboard Cite

show abstract

ChemInform Abstract: Synthesis of Phosphate Bridged D‐Glucose Units as Part of Phosphorylated Starch.

Franzkowiak¹,

Thiem²,

Demoulin³

1987

ChemInform

View full text Add to dashboard Cite

Radical Rearrangements of 2‐O‐(Diphenoxyphosphoryl)glycosyl Bromides

Koch

Giese

1993

Helvetica Chimica Acta

View full text Add to dashboard Cite

A variety of 2-deoxy-1-0-diphenoxylphosphoryl-hexopyranoses were generated in situ by a radical 2+ 1 migration of the phosphate group. The structures of the reactive rearrangement products were fully elucidated by NMR spectroscopy. Rate constants for this new rearrangement were determined for a variety of substrates.Introduction. -The radical 2+ 1 migration of acyloxy groups in glycosyl radicals is a well known reaction [I]. Recently, we and Crich and Yao published studies [2] on the hitherto unknown radical rearrangement of diphenoxyphosphoryl groups. As radical precursors, 3,4,6-tri-O -acetyl-2-0 -(diphenoxyphosphoryl)-a -D-glucopyranosyl bromide (1 ; -+ 2, see Scheme I) and 3,5-di-0 -benzoyl-2-0 -(diphenoxyphosphoryl)-D-ribofuranosy1 bromide were examined. The full extent of this new rearrangement has now been demonstrated by studies on other pyranose radical precursors.

show abstract

Synthese phosphat-verbrückter d-glucose-einheiten als teilstrukturen phosphorylierter stärken

Cited by 7 publications

References 37 publications

Synthesis of a non-natural glucose-2-phosphate ester able to dupe the acc system of Agrobacterium fabrum

Synthesis of a non-natural glucose-2-phosphate ester able to dupe the acc system of Agrobacterium fabrum

ChemInform Abstract: Synthesis of Phosphate Bridged D‐Glucose Units as Part of Phosphorylated Starch.

Radical Rearrangements of 2‐O‐(Diphenoxyphosphoryl)glycosyl Bromides

Contact Info

Product

Resources

About