Synthese und Struktur von Natriumoligophosphandiiden im System PhPCl₂/Na

Insights into the Chemistry of Transient P‐Chlorophosphanyl Complexes

“…Interesting follow-up reactions involving rearrangement and decomposition processes of III have been observed. In contrast, knowledge about derivatives IV, [9,10] which have potential leaving groups, is extremely scarce and, to the best of our knowledge, its coordination chemistry is unknown. The latter is of special interest, as open-shell complexes have been recognized as highly interesting targets, for example as contrast agents for molecular imaging.…”

Coordination Chemistry of the cyclo‐(P5tBu4)− Ion: Monomeric and Oligomeric Copper(I), Silver(I) and Gold(I) Complexes

“…Complexes 3-7 were characterised by 31 P NMR spectroscopy, and X-ray crystal structures were determined for 3-9. Keywords: copper · gold · P ligands · phosphorus · silver 2-4) [10] and have reported the synthesis of the first copper(I) oligophosphanide complex [Cu 4 A C H T U N G T R E N N U N G (P 4 Ph 4 ) 2 A C H T U N G T R E N N U N G (PCyp 3 ) 3 ], which was obtained from the reaction of two equivalents of [CuCl-A C H T U N G T R E N N U N G (PCyp 3 ) 2 ] with one equivalent of [Na 2 A C H T U N G T R E N N U N G (thf) 5 A C H T U N G T R E N N U N G (P 4 Ph 4 )]. [11] Inspired by this result, we have now studied the reactivity of [NaA C H T U N G T R E N N U N G {cyclo-A C H T U N G T R E N N U N G (P 5 tBu 4 )}] (1) with copper(I), silver(I) and gold(I) halides.…”

Synthesis and Molecular Structure of the Cu4P8 Cage Compound [Cu4(P4Ph4)2(PCyp3)3]

“…In contrast, the (P n R n ) 2− chains do not remain intact in transmetalations of K 2 (P 2 t Bu 2 ) with [NiCl 2 (PMe 3 ) 2 ], and of M 2 (P n Ph n ) ( n =2–4) with [Cp 2 M′Cl 2 ] (M′=Ti, Zr, Hf) 9. 10 Recently, the renaissance of oligophosphanide chemistry has been spurred by the targeted synthesis of Na[ cyclo ‐(P 5 t Bu 4 )], which displays highly versatile coordination chemistry,14, 15 and by the simplified syntheses of alkali metal oligophosphanediides M 2 (P n R n ) ( n =2–4),16–18 which have enabled detailed structural investigations thereof 16–20. In the context of our ongoing studies on the synthesis of metal complexes containing oligophosphanide ligands,14–21 we now report the synthesis and structural characterization of [Cu 4 (P 4 Ph 4 ) 2 (PCyp 3 ) 3 ] ( 1 ; Cyp= cyclo ‐C 5 H 9 ), which to our knowledge is the first copper( I ) complex with an oligophosphanediide ligand.…”