Syntheses and structural characterization of organotin(IV) complexes derived from the self-assembly of 2,4-diethylglutaric acid, phthalyl-glutamic acid and trialkyltin salts

Ma, Chunlin; Zhang, Shao‐Liang; Zhang, Rufen

doi:10.1016/j.jorganchem.2011.11.037

Cited by 9 publications

(2 citation statements)

References 29 publications

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“…Organotin compounds are widely used in industrial and agricultural production such as polyvinyl chloride (PVC) stabilizers, biocides, acaricides, catalysts, and surface curing agents (Davies et al, 2008). Organotin carboxylates, a class of organotin compounds, have been attracting great attention because of their structural diversity and biological properties, particularly anti-tumor activity (Tiekink, 1994;Ma et al, 2005Ma et al, , 2012Davies et al, 2008;Hadjikakou and Hadjiliadis, 2009;Amir et al, 2014). Triorganotin carboxylates usually possess discrete structures and chain or macro-cyclic structures formed by the carboxylate ligand bridging two tin centers (Sn-O-C=O→Sn) (Tiekink, 1994;Chandrasekhar et al, 2002;Davies et al, 2008).…”

Section: Introductionmentioning

confidence: 99%

“…Triorganotin carboxylates usually possess discrete structures and chain or macro-cyclic structures formed by the carboxylate ligand bridging two tin centers (Sn-O-C=O→Sn) (Tiekink, 1994;Chandrasekhar et al, 2002;Davies et al, 2008). A large variety of triorganotin carboxylates from aliphatic and aromatic carboxylic acids were synthesized and structurally characterized by X-ray single diffractions (Tiekink, 1994;Chandrasekhar et al, 2002;Davies et al, 2008;Shang et al, 2011;Ma et al, 2012;Amir et al, 2014, Zhang et al, 2014. Recently, we also reported the syntheses and crystal structures of some triorganotin carboxylates (Tian et al, 2013(Tian et al, , 2015Dong et al, 2014;Zhang et al, 2016;Yao et al, 2017).…”

Section: Introductionmentioning

confidence: 99%

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Syntheses and crystal structures of three bis(triorganotin) benzenedicarboxylates

Liu

Wang

et al. 2018

Main Group Metal Chemistry

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Three bis(triorganotin) benzenedicarboxylates, 1,n-C6H4(COOSnR3)2 (n, R=3, C6H5C(CH3)2CH2, 1; 4, C6H5C(CH3)2CH2, 2; 4, C6H11-c, 3), were synthesized by the reaction of 1,3 or 1,4-benzenedicarboxylic acid with triorganotin chlorides in the solution of CH3ONa-CH3OH and characterized by means of elemental analysis, Fourier-transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR) (1H, 13C, and 119Sn) spectra, and X-ray single-crystal diffraction. Compounds 1–3 are all di-nuclear tin complexes in which the carboxylate is monodentate and each tin atom possesses a distorted SnC3O tetrahedral geometry.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Syntheses and crystal structures of three bis(triorganotin) benzenedicarboxylates

Liu

Wang

et al. 2018

Main Group Metal Chemistry

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Synthesis, characterization and antimicrobial activity of triorganotin(IV) derivatives of some bioactive Schiff base ligands

Bhatra

Sharma

et al. 2016

Applied Organom Chemis

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Triorganotin(IV) complexes of the type Me3Sn[OC(R1):CH(CH3)C:NR2OH] and Ph3Sn[OC(R′):CH(CH3)C:NR″OH] (R′ = ─CH3, ─C6H5; R″ = ─(CH2)2─, ─(CH2)3─) have been synthesized by the reactions of trimethyl/phenyltin(IV) chloride with the sodium salt of corresponding Schiff base ligands in unimolar ratio in refluxing tetrahydrofuran. All these compounds have been characterized using elemental analyses and their probable structures have been proposed on the basis of infrared, 1H NMR, 13C NMR, 119Sn NMR and mass spectroscopic studies. In the trimethyltin(IV) derivatives the central tin atom is tetracoordinated, whereas in the analogous triphenyltin(IV)derivatives the central tin atom is pentacoordinated. All these ligands, metal precursors and corresponding triorganotin(IV) complexes have been screened for antimicrobial activities. A comparison of activities of the ligands and their corresponding triorganotin(IV) derivatives has been made. Attempts have also been made to relate the activity to the structure of these compounds.

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Structure and applications of organotin complex based on trimethyltin cation and quinaldic acid

El‐bendary

Etaiw

2017

Applied Organom Chemis

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The reaction between aqueous solution of Me3SnCl and acetonitrile solution of quinaldic acid (quinH) at room temperature affords a new organotin complex, [Me3Sn(quinH)(quin)]⋅6H2O (1). Complex 1 was structurally characterized using infrared, UV–visible and NMR spectra, thermogravimetric analysis and single‐crystal X‐ray analysis. The network structure of 1 is developed by a limitless number of discrete mononuclear molecules forming a one‐dimensional chain via hydrogen bonds. Extensive hydrogen bonds and π–π stacking associate the one‐dimensional chains creating a two‐dimensional array. The two‐dimensional arrays are additionally associated via hydrogen bonds through the water molecules and the methyl groups forming a three‐dimensional network. The cytotoxic impact of 1 on the viability of MCF‐7 cells was also examined using MTT assay, exhibiting great inhibiting action against MCF‐7 cells. Furthermore, the catalytic degradation performance of 1 towards methylene blue dye in the presence of H2O2 as oxidant was investigated. The reaction is first order with respect to methylene blue dye.

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Syntheses and structural characterization of organotin(IV) complexes derived from the self-assembly of 2,4-diethylglutaric acid, phthalyl-glutamic acid and trialkyltin salts

Cited by 9 publications

References 29 publications

Syntheses and crystal structures of three bis(triorganotin) benzenedicarboxylates

Syntheses and crystal structures of three bis(triorganotin) benzenedicarboxylates

Synthesis, characterization and antimicrobial activity of triorganotin(IV) derivatives of some bioactive Schiff base ligands

Structure and applications of organotin complex based on trimethyltin cation and quinaldic acid

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