Syntheses and structures of Ag(I) complexes containing 1,4-bis(4,5-dihydro-2-oxazolyl)benzene

Wang, Yueh-Hua; Lee, Hsun-Tsing; Suen, Maw‐Cherng

doi:10.1016/j.poly.2008.01.001

Cited by 17 publications

(13 citation statements)

References 58 publications

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“…For background to coordination polymers with organic ligands, see: Kitagawa et al (2004); Chiang et al (2008); ; Hsu et al (2009). For related structures, see: Wang et al (2008Wang et al ( , 2011; Suen et al (2011).…”

Section: Related Literaturementioning

confidence: 99%

“…Roles of anion, solvent and ligand comformations in self-assembly of coordination complexes containing polydentate nitrogen ligands are very intersting (Chiang et al, 2008;Yeh et al, 2008;Hsu et al, 2009;. The d 10 metal complexes containing 1,4-bis(4,5-dihydro-2-oxazolyl)benzene ligands (L′) have been reported, which show various two-dimensional networks (Wang et al, 2008, Wang et al, 2011. The Ag + cations are coordinated with two N atoms from two 1,2-bis(4,4-dimethyl-4,5-dihydrooxazol-2-yl)ethane (L) ligands (…”

Section: S1 Commentmentioning

confidence: 99%

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catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ²N:N′] perchlorate hemihydrate]

Yeh

Huang²,

Lin³

et al. 2012

Acta Cryst E

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In the title coordination polymer, {[Ag(C12H20N2O2)]ClO4·0.5H2O}n, the AgI cation is coordinated by two N atoms from two 1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane (L) ligands in a nearly linear geometry [N—Ag—N = 171.07 (8)°]. The L ligand bridges adjacent Ag+ cations, forming a polymeric chain running along the c axis. The lattice water molecule is situated on a twofold rotation axis, and links to the perchlorate anion via an O—H⋯O hydrogen bond. The long Ag⋯O separation of 3.200 (4) Å indicates a weak interaction between the perchlorate anion and the AgI cation. Weak C—H⋯O hydrogen bonding occurs between the chain and the lattice water molecule and between the chain and perchlorate anions. Both five-membered rings of the L ligand display envelope conformations; in one five-membered ring, the flap C atom is disordered on opposite sides of the ring with occupancies of 0.65 and 0.35.

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Section: Related Literaturementioning

confidence: 99%

Section: S1 Commentmentioning

confidence: 99%

catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ²N:N′] perchlorate hemihydrate]

Yeh

Huang²,

Lin³

et al. 2012

Acta Cryst E

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“…For background to coordination polymers with organic ligands, see: Kitagawa et al (2004). For related structures, see: Wang et al (2008).…”

Section: Related Literaturementioning

confidence: 99%

“…E67, m881 The synthesis of metal coordination polymers has been a subject of intense research due to their interesting structural chemistry and potential applications in gas storage, separation, catalysis, magnetism, luminescence, and drug delivery (Kitagawa et al, 2004). The Ag I complexes containing 1,4-bis(4,5-dihydro-2-oxazolyl)benzene ligands has been reported, which show various two-dimensional networks (Wang et al, 2008)…”

Section: Sup-1mentioning

confidence: 99%

catena-Poly[[bis(nitrato-κO)copper(II)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ²N:N′]

et al. 2011

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In the title coordination polymer, [Cu(NO3)2(C12H12N2O2)]n, the CuII ion, situated on an inversion center, is coordinated by two O atoms from two nitrate anions and two N atoms from two 1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene (L) ligands in a distorted square-planar geometry. Each L ligand also lies across an inversion center and bridges two CuII ions, forming a polymeric chain running along the [101] direction. The three O atoms of the nitrate group are disordered over two positions in a 3:2 ratio.

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“…2LiCl, seguido da adição de brometo de alila, fornece a oxazolina 120 desejada com 78% de rendimento (Esquema 28)(HAAS et al, 2015). Essa interação entre a prata e aril oxazolinas já foi descrito na literatura(ZHAO et al, 2012;WANG;SUEN, 2008). O complexo III sofre troca de ligantes com nitrato para regenerar o catalisador, complexo IV(GUTIERREZ et al, 2016).…”

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Aplicação de amidetos metálicos na funcionalização de aril-2-oxazolinas de interesse sintético

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Syntheses and structures of Ag(I) complexes containing 1,4-bis(4,5-dihydro-2-oxazolyl)benzene

Cited by 17 publications

References 58 publications

catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ²N:N′] perchlorate hemihydrate]

catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ²N:N′] perchlorate hemihydrate]

catena-Poly[[bis(nitrato-κO)copper(II)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ²N:N′]

Aplicação de amidetos metálicos na funcionalização de aril-2-oxazolinas de interesse sintético

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Syntheses and structures of Ag(I) complexes containing 1,4-bis(4,5-dihydro-2-oxazolyl)benzene

Cited by 17 publications

References 58 publications

catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ2N:N′] perchlorate hemihydrate]

catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ2N:N′] perchlorate hemihydrate]

catena-Poly[[bis(nitrato-κO)copper(II)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ2N:N′]

Aplicação de amidetos metálicos na funcionalização de aril-2-oxazolinas de interesse sintético

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About

catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ²N:N′] perchlorate hemihydrate]

catena-Poly[[silver(I)-μ-1,2-bis(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)ethane-κ²N:N′] perchlorate hemihydrate]

catena-Poly[[bis(nitrato-κO)copper(II)]-μ-1,4-bis(4,5-dihydro-1,3-oxazol-2-yl)benzene-κ²N:N′]