Syntheses of mixed ligands complexes of Ru(II) with 4,4′-dicarboxy-2,2′-bipyridine and substituted pteridinedione and the use of these complexes in electrochemical photovoltaic cells

Anandan, Sambandam; Latha, S.; Maruthamuthu, P.

doi:10.1016/s1010-6030(02)00094-1

Cited by 16 publications

(6 citation statements)

References 74 publications

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“…This technique is not limited to the arena of OLED discovery, however, and it may have extensions in a multitude of other scientific avenues. For instance, TiO 2 -based photovoltaic cells, − photoinduced water-splitting, , biomolecular probes, , and chiral luminophores − all present intriguing opportunities for further exploration.…”

Section: Discussionmentioning

confidence: 99%

Accelerated Luminophore Discovery through Combinatorial Synthesis

Lowry

Hudson²,

Pascal³

et al. 2004

J. Am. Chem. Soc.

506

486

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A method for accelerating the discovery of ionic luminophores using combinatorial techniques is reported. The photophysical properties of the resulting transition-metal-based chromophores were compared against a series of analogous, traditionally prepared species. The strong overlap between these two sets confirms the identity of the parallel synthesis products and supports the truthfulness of the combinatorial results. Further support for the combinatorial method comes from the adherence of these complexes to the energy gap law. The relationship between the structure of a complex and its photophysical properties was also considered, and static DFT calculations were used to assess whether it is feasible to predict the luminescent behavior of novel materials.

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Section: Discussionmentioning

confidence: 99%

Accelerated Luminophore Discovery through Combinatorial Synthesis

Lowry

Hudson²,

Pascal³

et al. 2004

J. Am. Chem. Soc.

506

486

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“…A nanoporous TiO 2 semiconductor layer approximately 17 μm thick was coated onto FTO conducting glass of sheet resistance 10 / cm (BHEL, India) according to earlier reports [22][23][24].…”

Section: Methodsmentioning

confidence: 99%

Spray deposition and characterization of nanostructured Li doped NiO thin films for application in dye-sensitized solar cells

Joseph¹,

Saravanan²,

Bhagavathiachari³

et al. 2008

Nanotechnology

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Transparent conducting Li (0-5 wt%) doped NiO thin films with preferential growth along the (111) plane were deposited onto glass substrates by pyrolytic decomposition of nickel nitrate and lithium chloride precursors at 500 °C in air. The effect of Li concentration on the structural, optical and transport properties of NiO thin films was studied by x-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM), spectral transmittance, photoluminescence and linear four-probe resistivity. Activation energies as a function of Li concentration were deduced from the temperature dependent resistivity data measured in the range 300-448 K. The figure of merit was deduced by combining the spectral transmittance and sheet resistance values. The variation in properties of NiO thin film due to Li doping are discussed based on the above results. A dye-sensitized solar cell has also been fabricated for the optimized Li doped NiO thin film and the results are presented.

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“…In an exciting study, Anandan et al reported the synthesis of mixed ligands of Ru(II) complexes ( 258 – 262 ) with dcbpy and substituted pteridinedione and isoalloxazine as spectator ligands and their use in electrochemical photovoltaic cells. The MLCT bands of these complexes were broad and red-shifted compared to those of [Ru(dcbpy) 3 ] 4– .…”

Section: Ruthenium Photosensitizers Based On Bis(44′-dicarboxylic Aci...mentioning

confidence: 98%

“…192 Additionally, in the investigation of ruthenium bpy dyes 256 and 257, incorporating sulfur-donor bidentate ligands, revealed that the recombination kinetics of 256 were unexpectedly fast, which was attributed to the terminal CN on the ligand binding to TiO 2 . 193 In an exciting study, Anandan et al 194 reported the synthesis of mixed ligands of Ru(II) complexes (258−262) with dcbpy and substituted pteridinedione and isoalloxazine as spectator ligands and their use in electrochemical photovoltaic cells. The MLCT bands of these complexes were broad and red-shifted compared to those of [Ru(dcbpy) 3 ] 4− .…”

Section: Ruthenium Photosensitizers Based Onmentioning

confidence: 99%

Influence of Ancillary Ligands in Dye-Sensitized Solar Cells

et al. 2016

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Dye-sensitized solar cells (DSSCs) have motivated many researchers to develop various sensitizers with tailored properties involving anchoring and ancillary ligands. Ancillary ligands carry favorable light-harvesting abilities and are therefore crucial in determining the overall power conversion efficiencies. The use of ancillary ligands having aliphatic chains and/or π-extended aromatic units decreases charge recombination and permits the collection of a large fraction of sunlight. This review aims to provide insight into the relationship between ancillary ligand structure and DSSC properties, which can further guide the function-oriented design and synthesis of different sensitizers for DSSCs. This review outlines how the new and rapidly expanding class of chelating ancillary ligands bearing 2,2'-bipyridyl, 1,10-phenanthroline, carbene, dipyridylamine, pyridyl-benzimidazole, pyridyl-azolate, and other aromatic ligands provides a conduit for potentially enhancing the performance and stability of DSSCs. Finally, these classes of Ru polypyridyl complexes have gained increasing interest for feasible large-scale commercialization of DSSCs due to their more favorable light-harvesting abilities and long-term thermal and chemical stabilities compared with other conventional sensitizers. Therefore, the main idea is to inspire readers to explore new avenues in the design of new sensitizers for DSSCs based on different ancillary ligands.

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Syntheses of mixed ligands complexes of Ru(II) with 4,4′-dicarboxy-2,2′-bipyridine and substituted pteridinedione and the use of these complexes in electrochemical photovoltaic cells

Cited by 16 publications

References 74 publications

Accelerated Luminophore Discovery through Combinatorial Synthesis

Accelerated Luminophore Discovery through Combinatorial Synthesis

Spray deposition and characterization of nanostructured Li doped NiO thin films for application in dye-sensitized solar cells

Influence of Ancillary Ligands in Dye-Sensitized Solar Cells

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