2018
DOI: 10.1016/j.molstruc.2017.12.006
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Syntheses, structural characterization, and basic properties of unsymmetrically substituted biphenoquinones

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“…The suitability of diphenoquinones and their reduced forms for use as solid cathodic materials in batteries depends on many factors, including their stability during multiple cycles of charging and discharging, solubility in electrolytes, solid-state conductivity, and ability to form open structures that let ions enter or exit easily. Unfortunately, very few structures of diphenoquinones have been reported, and information about preferred patterns of molecular organization is scarce. Even without clear guidelines, however, bis­(diphenoquinone) 8 (Scheme ) and analogues stand out as attractive targets for synthesis, in part because the rigid cruciform shape of spiro­bifluorenes often disfavors effective molecular packing and leads to open structures. A related compound of interest is simple fluorenequinone 9 (Scheme ), which was reported in 1956 by Nenitzescu and Avram but not characterized extensively…”
Section: Resultsmentioning
confidence: 99%
“…The suitability of diphenoquinones and their reduced forms for use as solid cathodic materials in batteries depends on many factors, including their stability during multiple cycles of charging and discharging, solubility in electrolytes, solid-state conductivity, and ability to form open structures that let ions enter or exit easily. Unfortunately, very few structures of diphenoquinones have been reported, and information about preferred patterns of molecular organization is scarce. Even without clear guidelines, however, bis­(diphenoquinone) 8 (Scheme ) and analogues stand out as attractive targets for synthesis, in part because the rigid cruciform shape of spiro­bifluorenes often disfavors effective molecular packing and leads to open structures. A related compound of interest is simple fluorenequinone 9 (Scheme ), which was reported in 1956 by Nenitzescu and Avram but not characterized extensively…”
Section: Resultsmentioning
confidence: 99%