Syntheses, structures and characteristics of four alkaline-earth metal-organic frameworks (MOFs) based on benzene-1,2,4,5-tetracarboxylicacid and its derivative ligand

Metal–organic frameworks based on infinite secondary building units: recent progress and future outlooks

“…Up to now, there are a few reports of alkaline earth metal (Ca, Sr and Ba)-based 2D MOFs. [61][62][63][64][65][66][67][68] In 2008, Loiseau et al 66 synthesized a 2D Ca-MOF-3 named [Ca 2 (OH) 2 (NDC), NDC ¼ 2,6naphathalenedicarboxylate] by reacting Ca(OH) 2 and H 2 NDC in the dilute HNO 3 solution at 180 C for 24 h. The obtained Ca-MOF-3 crystallized in the monoclinic and P2 1 /c space group. Each Ca 2+ was the 7-atom coordination with four carboxylate oxygen atoms from four NDC ligands and three hydroxyl groups (Fig.…”

Room Temperature Solid State Synthesis, Characterization, and Application of a Zinc Complex with Pyromellitic Acid

“…At the same time, the existence of aromatic ring in pyromellitic acid is conducive to the transfer of the electrons, which contributes to the preparation of optical, electrical and magnetic chemical materials [4][5][6][7]. The common synthetic method for this kind of complexes is the solvothermal method, and the complexes synthesized by this method have protean structures and superior performances [8,9]. However, there are some shortcomings for the method, such as difficult controls of synthetic conditions and difficulty in understanding the reaction process.…”

Effects of template molecules on the structures and luminescence intensities of a series of porous Tb-MOFs based on the 2-nitroterephthalate ligand

“…6 Multi-carboxylate ligands have been employed in the preparation of MOFs due to the varied coordination modes of the carboxyl group. 7 Bicarboxylate functional ligands, such as terephthalate and its derivatives, have been used in the construction of a great deal of MOFs as rigid spacers. 8 Furthermore, different auxiliary co-ligands containing nitrogen, such as bipyridine, also have been used to adjust structural features and properties.…”